5827-83-8

Basic information

• Product Name: dimethylamine picrate
• CAS NO: 5827-83-8
• Molecular Weight: 274.19
• Mol File: 5827-83-8.mol

Chemical Properties

• CAS DataBase Reference: dimethylamine picrate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethylamine picrate(5827-83-8)
• EPA Substance Registry System: dimethylamine picrate(5827-83-8)

Safety Data

• Hazardous Substances Data: 5827-83-8(Hazardous Substances Data)

Upstream product

• 598-94-7 1,1-Dimethylurea 
• 88-89-1 2,4,6-Trinitrophenol 
• 1332869-46-1 (E)-1,1,4,4-tetramethyl-2-tetrazenium picrate 
• 2129-20-6 bis(dimethylamino)sulfide 

Relevant articles and documents

Synthesis and stability of 2-tetrazenium salts

The geometry and electronic structure of (E)-N4Me4 (1) and the (E)-N4Me4H+ and the (E)-N 4Me5+ cations was examined by a DFT approach. By using the B3LYP/6-31+G(d,p) model we showed that the terminal nitrogen atoms in 1 are strongly basic, as evidenced by their highly negative NBO charges in comparison to the azo nitrogen atoms. Interestingly, protonation of 1 to form the (E)-N4Me4H+ cation does not result in significant changes in the NBO charges of the protonated nitrogen atom, which is in contrast with classical views that describe tetracoordinated nitrogen atoms as being positively charged. Insight into the thermal stability of salts of the (E)-N4Me4H+ and the (E)-N4Me 5+ cations was gained experimentally by DSC measurements of two salts of the (E)-N4Me4H+ cation, namely with chloride (2) and picrate (3) anions and the iodide salt of the (E)-N 4Me5+ cation (4), which were synthesized by protonation of 1 with hydrochloric (2) and picric (3) acids and by methylation of 1 with methyl iodide (4), respectively. Compounds 2-4 were characterized by analytical (elemental analysis and mass spectrometry) and spectroscopic ( 1H/13C NMR, IR/Raman and UV spectroscopies) methods. Protonation and methylation of 1 to form the (E)-N4Me 4H+ (compounds 2 and 3) and (E)-N4Me 5+ (compound 4) cations, respectively, appears to occur at the terminal nitrogen atoms, in keeping with the results of the NBO analysis and the higher stabilization energy of the conformations with a protonated/methylated terminal nitrogen atom. The geometry optimization by the B3LYP/6-31+G(d,p) method points at very weak N3-N4 bonds (N4 = protonated/methylated nitrogen atom), which explains the formation of dimethylammonium picrate in the thermal decomposition of picrate salt 3 and suggests that dialkylaminium radicals (R2N+) are involved in the decomposition pathway.

HYDROGEN BONDED COMPLEXES IV; UREA-PHENOL COMPLEXES

A number of crystalline, hydrogen-bonded complexes of ureas and phenols are reported.The most commonly observed urea-phenol ratio is 1:1, but some complexes with ratios of 2:1, 1:2 and 1:3 were encountered.The structures of these complexes are discussed and one degradative reaction is described.