58276-68-9

Upstream product

• 18077-05-9 trichloro-(1,1-dichloro-ethyl)-silane 
• 108-88-3 toluene 
• 622-97-9 1-ethenyl-4-methylbenzene 

Downstream Products

• 536-50-5 CH₃C₆H₄CH(CH₃)OH 
• 536-50-5 (S)-1-(4-Methylphenyl)ethanol 
• 42070-92-8 (R)-1-(4-methylphenyl)ethanol 

Relevant academic research and scientific papers

ACTIVATED HALO-CONTAINING ARALKYLSILANE

The invention is directed to an activated halo-containing aralkylsilanes possessing at least one hydrolyzable group bonded to a silicon atom and at least one halo functional group bonded to a carbon atom to which both the silicon atom and an aromatic grou

ACTIVATED HALO-CONTAINING ARALKYLSILANE COMPOSITION, PROCESS OF PREPARING SAME AND RUBBER COMPOSITIONS MADE THEREFROM

The invention is directed to an activated halo-containing aralkylsilanes possessing at least one hydrolyzable group bonded to a silicon atom and at least one halo functional group bonded to a carbon atom to which both the silicon atom and an aromatic group are covalently bonded. The invention is also directed to a process for making such a silane as well as its use in rubber compositions and articles containing such rubber compositions, such as tires.

Synthesis and application of bulky phosphoramidites: Highly effective monophosphorus ligands for asymmetric hydrosilylation of styrenes

A series of bulky monodentate phosphoramidite ligands were synthesized from chiral 3,3′-diaryl substituted BINOL derivatives and achiral or dendritic amines in good yields. Asymmetric hydrosilylation of styrenes with trichlorosilane in the presence of palladium complexes of these bulky ligands gave chiral silanes in high yields with excellent activity and productivity. Oxidation of these chiral silanes with hydrogen peroxide gave the corresponding chiral secondary alcohols in up to 96% ee.