58293-86-0Relevant academic research and scientific papers
A preparative route to methyl 3-(heteroaryl)acrylates using Heck methodology
Kwok, Thomas J.,Virgilio, Joseph A.
, p. 694 - 696 (2012/12/25)
Methyl 3-(heteroaryl)acrylates were prepared using Heck coupling of heteroarene halides with methyl acrylate mediated by Pd(OAc)2/ P(OCH3)3. Reactions were highly efficient (reaction times between 60 and 120 min) and scalable to 100 g of heteroarene halide. The isolated yields are from 76 to 99%.
PALLADIUM-CATALYZED COUPLINGS OF HALOFURANS WITH ACTIVATED ALKENES AND TERMINAL ALKYNES. A SHORT SYNTHESIS OF DIHYDROWYERONE
Crisp, Geoffrey T.,O'Donoghue, Ana I.
, p. 1745 - 1758 (2007/10/02)
The palladium-catalyzed coupling of bromofurans with activated alkenes and of furanoyl chlorides with either terminal alkynes or alkynyl stannanes gave good yields of the corresponding vinyl furans and alkynyl ketones.These studies culminated in a short s
Process for preparation of substituted olefins
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, (2008/06/13)
The present invention relates to a process for the preparation of aromatic or furyl substituted olefins, which comprises reacting an olefinic compound with an aromatic compound or furan compound in the presence of carbon monoxide by using a rhodium carbonyl complex as a catalyst to form a corresponding aromatic or furyl substituted olefin.
