611-13-2Relevant articles and documents
Oxidative esterification of renewable furfural on cobalt dispersed on ordered porous nitrogen-doped carbon
Yin, Defeng,Zheng, Yanxia,Yang, Lixi,Li, Shuyue,Zhu, Daqing,Guo, Yafei,Zuo, Cuncun,Li, Yuchao,Huang, Haofei,Wang, Ming
, p. 3280 - 3287 (2021)
A series of highly dispersed cobalt-based catalysts on N-doped ordered porous carbon (Co-NOPC) were synthesized using the sacrificiallate method. MCM-41, ZSM-5 and SBA-15 were employed as hard templates with 2,2′-bipyridine as the ligand. The physical and
On the nature of the active sites in the selective oxidative esterification of furfural on Au/ZrO2 catalysts
Ampelli,Barbera,Centi,Genovese,Papanikolaou,Perathoner,Schouten,van der Waal
, p. 127 - 134 (2016)
Two catalysts, based on gold on zirconia and prepared in the same way, except for the different thermal treatment in air after the addition of gold (0.4% wt), show a quite different behavior in furfural oxidative esterification, particularly in the select
Ultrahigh-Content Nitrogen-doped Carbon Encapsulating Cobalt NPs as Catalyst for Oxidative Esterification of Furfural
Wang, Ting,Ma, Hong,Liu, Xin,Luo, Yang,Zhang, Shujing,Sun, Yuxia,Wang, Xinhong,Gao, Jin,Xu, Jie
, p. 1515 - 1522 (2019)
It is an attractive and challenging topic to endow non-noble metal catalysts with high efficiency via a nitrogen-doping approach. In this study, a nitrogen-doped carbon catalyst with high nitrogen content encapsulating cobalt NPs (CoOx@N-C(g))
A tunable process: Catalytic transformation of renewable furfural with aliphatic alcohols in the presence of molecular oxygen
Tong, Xinli,Liu, Zonghui,Yu, Linhao,Li, Yongdan
, p. 3674 - 3677 (2015)
The tunable transformation of renewable furfural with aliphatic alcohols in the presence of O2 is developed. Based on a nano Au catalyst and potassium carbonate, a 91.8% yield of methyl 2-furoate with 98.7% selectivity is obtained via the oxidative esterification in a furfural-methanol-O2 system; while a 91.4% yield of 3-(furan-2-yl-)-2-methylacrylaldehyde with 97.2% selectivity is attained via the oxidative condensation in a furfural-n-propanol-O2 system. This journal is
Oxidation of furfural with H2O2 in the presence of a photogenerated iron catalyst
Moulines, Francoise,Ruiz, Jaime,Astruc, Didier
, p. C13 - C14 (1988)
Visible irradiation of a methanolic solution of furfural containing dilute aqueous H2O2 and PF6 (1: R=H, Cl or CH3) as catalyst yields methyl 2-furoate quantitatively.After photodecomplexation, the inorganic FeII,III catalyst can b
Method for preparing carboxylic ester compounds by oxidizing and breaking carbon-carbon bonds of secondary alcohol compounds
-
Paragraph 0078-0079; 0092, (2021/06/02)
The invention discloses a method for preparing carboxylic ester compounds by oxidizing and breaking carbon-carbon bonds of secondary alcohol compounds. The method comprises the following steps: adding a secondary alcohol compound, an additive and a nitrogen-doped mesoporous carbon loaded monatomic catalyst into a fatty primary alcohol solvent, putting into a pressure container, sealing, introducing oxygen source gas with a certain pressure, controlling the pressure of the oxygen source gas to be 0.1-1 MPa and the reaction temperature to be 80-150 DEG C, and obtaining a product after the reaction to be the carboxylic ester compound. The nitrogen-doped mesoporous carbon-loaded monatomic catalyst adopted by the invention is high in activity, the highest separation yield of the carboxylic ester compound as a reaction product reaches 99%, the method is wide in application range, the reaction conditions are easy to control, the catalyst can be recycled, the post-treatment is simple, and the method is suitable for industrial production.
One-pot synthesis of dimethyl succinate from D-fructose using Amberlyst-70 catalyst
He, Liangtu,Huang, Yuzhang,Len, Christophe,Liu, Lei,Miao, Xinge,Wang, Yantao,Yang, Weiran
, (2021/05/19)
Dimethyl succinate (DMS), an important building block of bio-based platform chemicals, was produced from D-fructose under one-pot and metal-free conditions for the first time. In the presence of 1.5 mmol D-fructose, 75 mg Amberlyst-70 and 10 bar O2/
