58308-07-9Relevant academic research and scientific papers
A convenient synthesis of some new 2-oxazolidone derivatives
Hussaini, Syed Sulaiman,Sriraman,Huq
, p. 249 - 250 (2007/10/03)
One of the general approaches to the synthesis of 2-oxazolidones involves the reaction of glycols with urea. The synthesis of some novel 2-oxazolidone derivatives 3, 5a and 5b hy the reaction of 1, 2 diols 2, 4a and 4h with urea have been reported.
C-C Bond Cleavage in O-Centered Mono- and Dianions Derived from α-Dicarbonyl Compounds
Varea, Teresa,Medio, Mercedes,Ballesteros, Rafael,Oniga, Ovidiu,Asensio, Gregorio
, p. 10093 - 10100 (2007/10/02)
The reaction of organolithium compounds with oxalyl derivatives and cyclic 1,2-dicarbonyl compounds leads to pinacols or ketones derived from homolytic C-C bond cleavage of the intermediate O,O-centered pinacol dianions depending on the ability of the substituents for the stabilisation of the resulting radical anion.The homolysis is induced by electrostatic repulsion of the negatively charged oxygen atoms.
