58322-08-0

Basic information

• Product Name: Phosphine oxide, 2-butenyldiphenyl-, (Z)-
• CAS NO: 58322-08-0
• Molecular Formula: C16H17OP
• Molecular Weight: 256.284
• Mol File: 58322-08-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Phosphine oxide, 2-butenyldiphenyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine oxide, 2-butenyldiphenyl-, (Z)-(58322-08-0)
• EPA Substance Registry System: Phosphine oxide, 2-butenyldiphenyl-, (Z)-(58322-08-0)

Safety Data

• Hazardous Substances Data: 58322-08-0(Hazardous Substances Data)

Upstream product

• 2129-89-7 diphenyl(methyl)phosphine oxide 
• 1079-66-9 chloro-diphenylphosphine 
• 598-32-3 2-hydroxy-3-butene 
• 62412-23-1 2.6-Dichlorbenzoesaeure-(Z)-2-butenylester 
• 829-85-6 diphenylphosphane 

Downstream Products

• 114678-86-3 (1'RS,2'E,3SR)-3-<3'-(diphenylphosphinoyl)-1'-methylprop-2'-enyl>cyclopentanone 
• 1551-67-3 1-[(Z)-2'-butenylidene]cyclohexane 

Relevant articles and documents

Epoxysilanes as substrates in regio- and stereo-specific synthesis of silylated γ-hydroxyphosphane oxides, precursors of stereodefined allylphosphane oxides

Epoxysilanes experienced trans stereospecific α- or β-cleavage by the lithium derivative of methyldiphenylphosphane oxide leading to different compounds. The behaviour of the epoxysilanes towards this nucleophilic reagent depends on the nature of the sily

Asymmetric dihydroxylations of allylic phosphine oxides

Allylic phosphine oxides 6 undergo asymmetric dihydroxylation to yield 1,2 diols 9. The enantioselectivity of these reactions depends critically on the class and quantity of chiral ligand used. A model to explain the sense and degree of asymmetric inducti