58372-28-4Relevant academic research and scientific papers
On Conformational Sensitivity in the Ultraviolet Spectra of Cyclopropyl Ketones and Olefins
Van-Catledge, Frederic A.,Boerth, Donald W.,Kao, James
, p. 4096 - 4106 (2007/10/02)
Selected cyclopropyl ketones and olefins have been prepared to approximate the three principal conformers (s-trans, s-cis, and gauche) of vinylcyclopropane and cyclopropanecarboxaldehyde.The model systems are as follows: for the s-cis form, 4-oxo- (VI) an
Aldol Reaction of Aluminium Enolate Resulting from 1,4-Addition of R2AlX to α,β-Unsaturated Carbonyl Compound. A 1-Acylethenyl Anion Equivalent
Itoh, Akira,Ozawa, Shuji,Oshima, Koichiro,Nozaki, Hitosi
, p. 274 - 278 (2007/10/02)
Organoaluminium reagents R2AlX (X=SPh, SeMe) easily add to α,β-unsaturated carbonyl compounds in 1,4-fashion.The resulting aluminium enolates react with aldehydes to give aldol adducts in fair to good yields.Formal elimination of HX from the adducts provi
