74457-11-7Relevant academic research and scientific papers
A General Synthesis of 2-Substituted Cyclohex-2-enones
Armitage, Mark A.,Lathbury, David C.,Mitchell, Michael B.
, p. 1551 - 1552 (2007/10/02)
A new synthesis of 2-substituted cyclohex-2-enones has been achieved using a sequence involving the aldol reaction of the aluminium enolate derived from thiolate addition to cyclohex-2-enone, followed by dehydration, rearrangement and desulfurisation.
Aldol Reaction of Aluminium Enolate Resulting from 1,4-Addition of R2AlX to α,β-Unsaturated Carbonyl Compound. A 1-Acylethenyl Anion Equivalent
Itoh, Akira,Ozawa, Shuji,Oshima, Koichiro,Nozaki, Hitosi
, p. 274 - 278 (2007/10/02)
Organoaluminium reagents R2AlX (X=SPh, SeMe) easily add to α,β-unsaturated carbonyl compounds in 1,4-fashion.The resulting aluminium enolates react with aldehydes to give aldol adducts in fair to good yields.Formal elimination of HX from the adducts provi
ALDOL REACTION OF ALUMINIUM ENOLATE RESULTING FROM 1,4-ADDITION OF Me2AlSPh TO α,β-UNSATURATED CARBONYL COMPOUND. A 1-ACYLETHENYL ANION EQUIVALENT
Itoh, Akira,Ozawa, Shuji,Oshima, Koichiro,Nozaki, Hitosi
, p. 361 - 364 (2007/10/02)
Me2AlSPh or Me2AlSeMe adds to α,β-unsaturated carbonyl compounds in 1,4-fashion.The resulting aluminium enolates react with aldehydes effectively to afford the adducts of the title anion after formal PhSH (or MeSeH)-elimination
