58431-65-5

Upstream product

• 7205-91-6 phenylthiomethyl chloride 
• 13884-92-9 phenylthiomethyl triphenylphosphonium chloride 
• 78-84-2 isobutyraldehyde 
• 17101-71-2 Z-β-bromovinyl phenyl sulfide 
• 1068-55-9 isopropylmagnesium chloride 
• 126798-71-8 phenylthiomethyltriphenylarsine iodide 

Relevant academic research and scientific papers

STEREOSPECIFIC SYNTHESIS OF ALKENYL SULPHIDES BY CROSS-COUPLING REACTIONS OF SECONDARY ALKYL GRIGNARD REAGENTS WITH Z- OR E-1-BROMO-2-PHENYLTHIOETHENE IN THE PRESENCE OF TRANSITION METAL CATALYSTS

Z- and E-1-bromo-2-phenylthioethenes were cross-coupled stereospecifically with s-alkyl Grignard reagents in the presence of a series of NiII, PdII, or FeIII catalysts with the aim of finding a catalyst which would not cau

Homologation of aldehydes using (phenylthiomethylene) triphenylarsorane: Selective preparation of α-thiophenoxyepoxides and phenylthioenol ethers

The title arsonium ylide reacts with aldehydes to give exclusively α-thiophenoxyepoxides in THF and phenylthioenol ethers in THF/HMPA. The former adducts are readily transformed to α-thiophenoxy carbonyls and the latter to one-carbon homologated aldehydes.