58451-85-7 Usage
Uses
Used in Organic Synthesis:
α,α,α',α'-Tetraphenyl-2,6-piperidinedimethanol is used as a reducing agent for its ability to stabilize free radicals, which is crucial in the preparation of various pharmaceuticals, polymers, and other organic compounds.
Used in Pharmaceutical Preparation:
In the pharmaceutical industry, α,α,α',α'-Tetraphenyl-2,6-piperidinedimethanol is utilized as a key component in the synthesis of drugs, leveraging its reducing properties to facilitate the formation of desired chemical structures.
Used in Polymer Production:
α,α,α',α'-Tetraphenyl-2,6-piperidinedimethanol is also employed in the production of polymers, where its reducing capabilities contribute to the formation of polymer chains with specific properties.
Used as a Chelating Agent:
α,α,α',α'-Tetraphenyl-2,6-piperidinedimethanol serves as a chelating agent in metal-catalyzed reactions, enhancing the efficiency of these processes by binding to metal ions and influencing the reaction pathways.
Used in Chemical Reactions for High Selectivity and Efficiency:
Due to its high selectivity and efficiency, α,α,α',α'-Tetraphenyl-2,6-piperidinedimethanol is a prized tool in various chemical reactions, particularly in the field of organic chemistry where precise control over reaction outcomes is essential.
Check Digit Verification of cas no
The CAS Registry Mumber 58451-85-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,8,4,5 and 1 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 58451-85:
(7*5)+(6*8)+(5*4)+(4*5)+(3*1)+(2*8)+(1*5)=147
147 % 10 = 7
So 58451-85-7 is a valid CAS Registry Number.
InChI:InChI=1/C31H31NO2/c33-30(24-14-5-1-6-15-24,25-16-7-2-8-17-25)28-22-13-23-29(32-28)31(34,26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21,28-29,32-34H,13,22-23H2
58451-85-7Relevant academic research and scientific papers
D?nges, Maike,Amberg, Matthias,Stapf, Georg,Kelm, Harald,Bergstr??er, Uwe,Hartung, Jens
, p. 120 - 134 (2014)
cis-2,6-Bis-(methanolate)-piperidine oxovanadium(V) complexes are Lewis acids able to catalyze oxidative cyclization of alkenols by tert-butyl hydroperoxide (TBHP). Terminal dimethyl-substituted (prenyl-type) 4-pentenols bearing an alkyl or a phenyl group in position 1 afford under such conditions 2,5-cis-derivatives of 2-(tetrahydrofuran-2-yl)-2-propanol as major and tetrahydropyran-3-ols as minor products (four examples). Oxidizing 1-phenyl-6-methylhept-5-en-1-ol yields a 75/25-mixture of the derived 2-(tetrahydropyran-2-yl)-2-propanol and an oxepan-3-ol, whereas 2-propenols give epoxides in up to 94% yield. Epoxidizing geraniol by TBHP in the presence of a vanadium catalyst prepared from (2S,6R)-2-diphenylmethanol-6- hydroxymethylpiperidine occurs enantioselectively. Highfield shifts of vanadium-51 resonances upon adding alkyl hydroperoxides to solutions of cis-2,6-bis-(methanolate)-piperidine vanadium(V) complexes point to vanadium(V) tert-butyl peroxy complex formation as key step for activating peroxides.
