5848-64-6

Basic information

• Product Name: HEXA-N-PROPYL PHOSPHOROUS TRIAMIDE
• Synonyms: P(N(n-C3H7)2)3;Phosphine, tris(dipropylamino)-;Tris(N,N-di-n-propylamino)phosphine;TIMTEC-BB SBB008178;TRIS(DIPROPYLAMINO)PHOSPHINE;HEXA-N-PROPYL PHOSPHOROUS TRIAMIDE;HEXAISOPROPYLPHOSPHORUS TRIAMIDE;Tris(di-n-propylamino)phosphine
• CAS NO: 5848-64-6
• Molecular Formula: C₁₈H₄₂N₃P
• Molecular Weight: 331.52
• Mol File: 5848-64-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 101-103°C 0,15mm
• Flash Point: 182.9°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 6.15E-06mmHg at 25°C
• PKA: 12.51±0.70(Predicted)
• CAS DataBase Reference: HEXA-N-PROPYL PHOSPHOROUS TRIAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: HEXA-N-PROPYL PHOSPHOROUS TRIAMIDE(5848-64-6)
• EPA Substance Registry System: HEXA-N-PROPYL PHOSPHOROUS TRIAMIDE(5848-64-6)

Safety Data

• Statements: R36/38:Irritating to eyes and skin.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36:Wear suitable prot
• Hazardous Substances Data: 5848-64-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C18H42N3P/c1-7-13-19(14-8-2)22(20(15-9-3)16-10-4)21(17-11-5)18-12-6/h7-18H2,1-6H3

Upstream product

• 81175-44-2 C₂₄H₅₆N₄P⁽¹⁺⁾*I^(1-) 
• 142-84-7 di-n-propylamine 
• 32597-23-2 dipropyl-amidophosphoric acid-dichloride 

Downstream Products

• 1020261-98-6 C₂₄H₄₇N₃PSe⁽¹⁺⁾*I^(1-) 
• 130632-32-5 2-Dipropylamino-1,3-diphenyl-[1,3,2]diazaphosphetidin-4-one 
• 102348-30-1 (2-Phenyl-2H-8-thia-1,2,3a-triaza-3-phospha-cyclopenta[a]inden-3-yl)-dipropyl-amine 
• 15545-56-9 N-phenyl-N',N'-di(n-propyl)urea 
• 131471-73-3 C₂₅H₄₅ClN₆P₂S 
• 142-84-7 di-n-propylamine 
• 131471-70-0 C₂₆H₄₈N₆P₂S 
• 128608-48-0 1-(1-Dipropylamino-6-phenyl-thiazolo[3,2-d][1,2,4,3]triazaphosphol-2-yl)-ethanone 
• 130632-40-5 2-Dipropylamino-benzo[1,3,2]oxazaphosphole-3-carboxylic acid phenylamide 
• 102348-34-5 C₂₅H₄₆N₆P₂S 

Relevant articles and documents

Syntheses and crystal structures of tris(di-n-propylamino)-p-bromobenzyl-phosphonium bromides: [(C3H7)2N]3PCH2C 6H4Br+Br- and [(C3H7)2N]3PCH2C 6H4Br+Br3-

Tris(di-n-propylamino)-p-bromobenzylphosphonium bromide [(C3H7)2N]3PCH2C 6H4Br+Br- (1) has been prepared by the reaction of tris(di-n-propylamino)phosphine with p-bromobenzylbromide in methylene chloride. The colorless crystals are monoclinic, space group P21, Z = 2, a = 930.2(3), b = 1501.2(3), c = 1093.5(2) pm, β = 105,97(4)°. The lattice contains Br- anions and [(C3H7)2N]3PCH2C 6H4Br+ cations. [(C3H7)2N]3PCH2C 6H4Br+Br3- (2) has been obtained by treating 1 with equimolar quantities of elemental bromine in methylene chloride solution. The yellow-red crystals of 2 are triclinic, space group P1?, Z = 2, a = 1069.5(3), b = 1267.7(7), c = 1273.7(3) pm, α = 87.27(3), β = 82,67, γ = 67.15°, and consist of [(C3H7)2N]3PCH2C 6H4Br+ cations and linear Br3- anions. The three N atoms in the cations of 2 are planar.

REDUCTION OF TETRAKIS(DIALKYLAMINO)PHOSPHONIUM HALIDES WITH SODIUM IN LIQUID AMMONIA

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