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58488-01-0

2-(acetoxymethyl)-2-methylcyclohexanone is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 58488-01-0 Structure

  • Basic information

    1. Product Name: 2-(acetoxymethyl)-2-methylcyclohexanone
    2. Synonyms: 2-(acetoxymethyl)-2-methylcyclohexanone
    3. CAS NO:58488-01-0
    4. Molecular Formula:
    5. Molecular Weight: 184.235
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 58488-01-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-(acetoxymethyl)-2-methylcyclohexanone(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-(acetoxymethyl)-2-methylcyclohexanone(58488-01-0)
    11. EPA Substance Registry System: 2-(acetoxymethyl)-2-methylcyclohexanone(58488-01-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 58488-01-0(Hazardous Substances Data)

58488-01-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 58488-01-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,8,4,8 and 8 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 58488-01:
(7*5)+(6*8)+(5*4)+(4*8)+(3*8)+(2*0)+(1*1)=160
160 % 10 = 0
So 58488-01-0 is a valid CAS Registry Number.

58488-01-0Relevant articles and documents

Highly selective acylation of alcohols and amines by an indium triiodide-catalysed transesterification process

Ranu, Brindaban C.,Dutta, Pinak,Sarkar, Arunkanti

, p. 2223 - 2225 (2000)

A very simple method has been developed for the acylation of alcohols and amines by ethyl acetate through an indium triiodide-catalysed transesterification process. Using this method acylation of a primary OH group in the presence of secondary and phenolic OH groups, and of a primary NH2 in the presence of secondary NH and primary OH have been achieved with high selectivity. The Royal Society of Chemistry 2000.

Some 6,6-disubstituted 2,4-cyclohexadien-1-ones and the facial selectivity in their Diels-Alder reactions with dimethyl acetylenedicarboxylate

Yates, Peter,Gomes, Anabela,Burnell, Jean D.,Cong, Dong Dao,Sawyer, Jeffery F.

, p. 37 - 47 (2007/10/02)

6,6-Disubstituted 2,4-cyclohexadien-1-ones can be prepared by dibromination-bisdehydrobromination of the corresponding 6,6-disubstituted 2,2-dibromocyclohexanones.Such dienes undergo Diels-Alder reactions with dimethyl acetylenedicarboxylate to give 3,3-disubstituted 5,6-di(methoxycarbonyl)bicycloocta-5,7-dien-2-ones; when the substituents at C-6 in the dienones are different, two diastereomers of the adducts are formed in a ratio dependent on the "facial selectivity" in the Diels-Alder reactions.For the cases where one of the 6-substituents is methyl and the other is methoxycarbonyl, acetoxymethyl, dibromomethyl, or dichloromethyl it has been established via X-ray crystallograpfy and chemical correlation that the endo-3-methyl/exo-3-methyl product ratio is 3.0, 0.9, 8, and 6, respectively.The origin of these differences is discussed briefly and a spectroscopic method for the assignment of structures to the individual diastereomers is proposed.Key words: Diels-Alder reactions, substituted 2,4-cyclohexadien-1-ones, facial selectivity, dimethyl acetylenedicarboxylate.

FUNCTIONALISATION OF UNACTIVATED METHYL GROUPS THROUGH CYCLOPALLADATION REACTIONS

Baldwin, Jack E.,Jones, Richard H.,Najera, Carmen,Yus, Miguel

, p. 699 - 712 (2007/10/02)

The transformation of the organopalladium compound (3) into the corresponding deuteriated, chlorinated, or oxidized derivatives (7), (8), or (9), (11), and (12) respectively, is described.The palladation of compound (9) takes place regioselectively leadin

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