58506-33-5

Basic information

• Product Name: (2E,4E)-5-PHENYL-PENTA-2,4-DIEN-1-OL
• Synonyms: (2E,4E)-5-PHENYL-PENTA-2,4-DIEN-1-OL
• CAS NO: 58506-33-5
• Molecular Formula: C₁₁H₁₂O
• Molecular Weight: 160.21238
• Mol File: 58506-33-5.mol
• Article Data: 47

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (2E,4E)-5-PHENYL-PENTA-2,4-DIEN-1-OL(CAS DataBase Reference)
• NIST Chemistry Reference: (2E,4E)-5-PHENYL-PENTA-2,4-DIEN-1-OL(58506-33-5)
• EPA Substance Registry System: (2E,4E)-5-PHENYL-PENTA-2,4-DIEN-1-OL(58506-33-5)

Safety Data

• Hazardous Substances Data: 58506-33-5(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 61, p. 2604, 1996 DOI: 10.1021/jo951923t

Upstream product

• 38447-05-1 (2E,4E)-methyl 5-phenylpenta-2,4-dienoate 
• 107-18-6 allyl alcohol 
• 890022-08-9 ethyl (4E)-5-phenylpenta-2,4-dienoate 
• 55666-17-6 (1E)-1,4-pentadienylbenzene 
• 112564-73-5 (2E)-1-phenyl-2,4-pentadiene-1-ol 
• 13466-40-5 5-phenylpenta-2,4-dienal 
• 1552-95-0 ethyl 5-phenyl-2,4-pentadienoate 
• 104-55-2 3-phenyl-propenal 
• 60329-12-6 2-phenylmethylenecyclopropylmethanol 
• 1516-24-1 methyl 5-phenylpenta-2,4-dienoate 
• 201230-67-3 2,4-pentanedienal 
• 103-26-4 Methyl cinnamate 
• 14371-10-9 (E)-3-phenylpropenal 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 

Downstream Products

• 143816-04-0 (2E,4E)-5-phenylpenta-2,4-dien-1-yl acetate 
• 109529-98-8 (5-bromopenta-1,3-dienyl)benzene 
• 1603020-79-6 C₁₃H₁₄O 

Relevant articles and documents

Oxoammonium-Mediated Allylsilane–Ether Coupling Reaction

A new C(sp3)?H functionalization reaction consisting of the oxidative α-allylation of allyl- and benzyl- methyl ethers has been developed. The C?C coupling could be carried out under mild conditions thanks to the use of cheap and green oxoammonium salts. The scope of the reaction was studied over 27 examples, considering the nature of the substituents on the two coupling partners.

Arene Trifunctionalization with Highly Fused Ring Systems through a Domino Aryne Nucleophilic and Diels–Alder Cascade

A convenient and efficient domino aryne process was developed under transition-metal-free conditions to generate a range of tetra- and pentacyclic ring systems. This transformation was realized via a 1,2-benzdiyne through a nucleophilic and Diels–Alder reaction cascade using styrene as the diene moiety. Three new chemical bonds, namely one C?N and two C?C bonds, and two benzofused rings could be constructed concomitantly, which was made possible by distinct chemoselective control at both the 1,2-aryne and 2,3-aryne stages. Moreover, in-depth studies were carried out on the domino aryne precursors and controlling the diastereoselectivity.

Palladium-catalyzed allylic C-H oxidation under simple operation and mild conditions

We discovered an effective and simple system (Pd/BQ/air/r.t.) for making allylic alcohols through Pd-catalyzed allylic C-H bond functionalization. This approach exhibits advantages due to its simple operation, mild conditions, and environmentally benign features. By modifying reaction conditions, it can be suitable for preparing unsaturated aldehydes, allylic esters, ethers, and amines.