5856-89-3

Basic information

• Product Name: Benzenamine, N-phenyl-, lithium salt
• CAS NO: 5856-89-3
• Molecular Formula: C12H11N.Li
• Molecular Weight: 175.159
• Mol File: 5856-89-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-phenyl-, lithium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-phenyl-, lithium salt(5856-89-3)
• EPA Substance Registry System: Benzenamine, N-phenyl-, lithium salt(5856-89-3)

Safety Data

• Hazardous Substances Data: 5856-89-3(Hazardous Substances Data)

Upstream product

• 122-39-4 diphenylamine 
• 109-72-8 n-butyllithium 
• 382165-80-2 N-nitrosodiphenylamine 

Downstream Products

• 603-34-9 N,N-diphenylaminobenzene 
• 340-97-6 N,N-Diphenyl- 
• 122-39-4 diphenylamine 
• 138852-88-7 1,1-dimethyl-1-pentafluorophenyl-N,N-diphenyl-silanamine 
• 165289-25-8 C₁₅H₁₇ClNP 
• 890534-61-9 N,N-diphenylaminocyclopropane 
• 4011-28-3 tetraphenylaminoborane 
• 141557-15-5 Li(CH₃OCH₂CH₂OCH₃)3⁽¹⁺⁾*CH₃C₅H₄Pr(N(C₆H₅)2)3^(1-)={Li(CH₃OCH₂CH₂OCH₃)3}{CH₃C₅H₄Pr(N(C₆H₅)2)3} 
• 141557-13-3 Li(CH₃OCH₂CH₂OCH₃)3⁽¹⁺⁾*CH₃C₅H₄La(N(C₆H₅)2)3^(1-)={Li(CH₃OCH₂CH₂OCH₃)3}{CH₃C₅H₄La(N(C₆H₅)2)3} 
• 141583-57-5 Li(CH₃OCH₂CH₂OCH₃)3⁽¹⁺⁾*CH₃C₅H₄Nd(N(C₆H₅)2)3^(1-)={Li(CH₃OCH₂CH₂OCH₃)3}{CH₃C₅H₄Nd(N(C₆H₅)2)3} 
• 907570-65-4 [U[(SiMe₂NPh)2-1,4,7-triazacyclononane]NPh₂] 
• 1194341-50-8 3-bromo-2-(diphenylamino)-4-fluorobenzonitrile 
• 1195901-15-5 2-bromo-N,N-diphenyl-5-(trimethylsilyl)-1,3-thiazol-4-amine 
• 1195901-22-4 diphenyl-(1,3,5-trimethyl-1H-pyrazol-4-yl)-amine 

Relevant articles and documents

E–H (E?=?N, O) bond activation by a nucleophilic palladium carbene

E–H bond cleavage by [{PC(sp2)P}Pd(PMe3)] (1, PC(sp2)P = iPr2P–C6H4–C–C6H4–PiPr2) of alcohols led to a series of new square-planar tri

Selective introducing of aryl and amino groups: Reaction of benzanthrone and organometallic reagents

The reaction of benzanthrone and aryl magnesium bromides produced 6-aryl-substituted benzanthrones in moderate to good yields. Similarly, 6-alkylaminobenzanthrones were selectively prepared by the reaction of benzanthrone and lithium alkylamides. In contrast, for the lithium arylamides, the arylamino groups were selectively introduced at the 4-position of the benzanthrone.

METHOD FOR THE PREPARATION OF A COMPOUND OF THE GENERAL FORMULA R1-R1 AND/OR R1-R2 USING HOMO AND HETERO COUPLING REACTIONS

The present application relates to a method for the preparation of a compound of the general formula R1-R2 (I) and/or R1-R1 (II) comprising providing a compound of the general formula R1dM1Am.zM4Zn (III) or R1R2M1R3kAm.xM4Zn (IV) or R1M1R2R3kM2Am.xM4Zn (V) or R1M3R2M1.xM4Zn (VI) and reacting this compound III-VI with a quinone to produce a compound of the general formula (I) or (II) or a mixture of compounds (I) and (II). The coupling reaction can be used to prepare homo and/or hetero coupling products from well known starting materials using a quinone as redox reagent. The quinone may be recycled from the reaction.