58565-19-8Relevant academic research and scientific papers
Copper-catalyzed aerobic aliphatic C-H oxygenation directed by an amidine moiety
Wang, Yi-Feng,Chen, Hui,Zhu, Xu,Chiba, Shunsuke
, p. 11980 - 11983 (2012/09/08)
A method for the oxygenation of tertiary C-H bonds of N-alkylamidines and N-(2-alkylaryl)amidines is described that utilizes the CuBr?SMe 2/2,2′-bipyridine catalytic system under an O2 atmosphere and provides dihydrooxazoles and 4H-1,3-benzoxazines. The oxygen atom is incorporated from atmospheric molecular oxygen during the present process.
Epoxides : Part I - Synthesis of β,β-Diaryl-N-substituted-ethanolamines and Morpholines
Moussa, G. E. M.,Basyouni, M. N.,Shaban, M. E.
, p. 798 - 800 (2007/10/02)
Benzyl-, butyl- and ethanol-amines attack the unsubstituted carbon atom of epoxides (I) to give the corresponding ethanol- and diethanol-amines (II).The diethanolamines (II, R=CH2OH) undergo cyclodehydration to give morpholines (III).II (R=Ph and n-Pr) ha
