36746-50-6Relevant academic research and scientific papers
Copper-catalyzed aerobic aliphatic C-H oxygenation directed by an amidine moiety
Wang, Yi-Feng,Chen, Hui,Zhu, Xu,Chiba, Shunsuke
, p. 11980 - 11983 (2012/09/08)
A method for the oxygenation of tertiary C-H bonds of N-alkylamidines and N-(2-alkylaryl)amidines is described that utilizes the CuBr?SMe 2/2,2′-bipyridine catalytic system under an O2 atmosphere and provides dihydrooxazoles and 4H-1,3-benzoxazines. The oxygen atom is incorporated from atmospheric molecular oxygen during the present process.
Regioselective Cycloadditions of N-Protonated Azomethine Ylides and 2-Azaallyl Anions Generated from N-(Silylmethyl) Thioimidates, Synthetic Equivalents of Nonstabilized Nitrile Ylides
Tsuge, Otohiko,Kanemasa, Shuji,Yamada, Toshiaki,Matsuda, Koyo
, p. 2523 - 2530 (2007/10/02)
A water-induced-desilylation method and a direct-desilylation method have been applied to N-(silylmethyl) thioimidates to lead to the generation of N-protonated azomethine ylides and 2-azaallyl anions, respectively.These reactive intermediates are capture
ACTION DES ORGANOMETALLIQUES SUR LES IMINOETHERS : NOUVELLE VOIE D'ACCES AUX OXAZOLINES.
Bellassoued, M.,Gaudemar, M.,Hajjem, B.,Baccar, B.
, p. 65 - 72 (2007/10/02)
Iminoethers of type 1 have been shown to react with organometallic reagents to give oxazolines in good yield.The process of the reaction is discussed.
