58585-35-6Relevant academic research and scientific papers
Preparation of secondary and tertiary amides under neutral conditions by photochemical acylation of amines
Helgen,Bochet
, p. 1968 - 1970 (2001)
The smooth and neutral acylation of amines to form amides by photoactivation of N-acyl-5,7-dinitroindolines is described. An improved acylation of nitroindolines allows the convenient preparation of N-acylnitroindolines. This reaction makes possible the recycling of the nitroindoline released during the photoactivation.
Photoacylation of alcohols in neutral medium
Debieux, Jean-Luc,Cosandey, Anne,Helgen, Celine,Bochet, Christian G.
, p. 2073 - 2077 (2008/02/04)
We report here conditions which allow the photoacylation of primary, secondary and tertiary alcohols with N-acetyl-5,7-dinitroindoline under exceptionally mild conditions, at wavelengths harmless to most functional groups, including otherwise photosensitive ones. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
