5864-44-8

Basic information

• Product Name: potassium diphenylamide
• Synonyms: potassium diphenylamide
• CAS NO: 5864-44-8
• Molecular Weight: 207.316
• Mol File: 5864-44-8.mol

Chemical Properties

• CAS DataBase Reference: potassium diphenylamide(CAS DataBase Reference)
• NIST Chemistry Reference: potassium diphenylamide(5864-44-8)
• EPA Substance Registry System: potassium diphenylamide(5864-44-8)

Safety Data

• Hazardous Substances Data: 5864-44-8(Hazardous Substances Data)

Upstream product

• 7440-09-7 potassium 
• 122-39-4 diphenylamine 

Downstream Products

• 603-34-9 N,N-diphenylaminobenzene 
• 4316-54-5 N,N-diphenyl-m-toluidine 
• 92899-33-7 N,N,N',N'-tetraphenyl-metha-benzenediamine 
• 606-99-5 N,N-diphenylethylamine 
• 6590-42-7 N-pentyl-N-phenylaniline 
• 105396-07-4 di-tert-butyl(diphenylamino)borane 
• 442574-01-8 bis(diphenylamido)ytterbium tetrakis(tetrahydrofuran) adduct 
• 1032475-59-4 C₄H₆N(C(CH₃)3)BN(C₆H₅)2 
• 1088378-01-1 (C₅Me₅)2U(NPh₂)(NC₆H₃(iPr)2-2,6) 
• 1227189-02-7 (P-C)Pd(THF)NPh₂ 
• 1227189-16-3 Pd(P(C(CH₃)3)2CH₂C₆H₄)N(C₆H₅)2 
• 145938-15-4 tetrakisdiphenylamide uranium(IV) 
• 36809-32-2 N-(4-trifluoromethylphenyl)-N-methylaniline 
• 14118-16-2 N,N,N',N'-tetraphenyl-p-phenylenediamine 

Relevant articles and documents

Insight into one-electron oxidation of the {Fe(NO)2}9 dinitrosyl iron complex (DNIC): Aminyl radical stabilized by [Fe(NO) 2] motif

A reversible redox reaction ({Fe(NO)2}9 DNIC [(NO)2Fe(N(Mes)(TMS))2]- (4) ? oxidized-form DNIC [(NO)2Fe(N(Mes)(TMS))2] (5) (Mes = mesityl, TMS = trimethylsilane)), characterized by IR, UV-vis, 1H/15N NMR, SQUID, XAS, single-crystal X-ray structure, and DFT calculation, was demonstrated. The electronic structure of the oxidized-form DNIC 5 (Stotal = 0) may be best described as the delocalized aminyl radical [(N(Mes)(TMS))2]2 -? stabilized by the electron-deficient {Fe III(NO-)2}9 motif, that is, substantial spin is delocalized onto the [(N(Mes)(TMS))2] 2-? such that the highly covalent dinitrosyl iron core (DNIC) is preserved. In addition to IR, EPR (g ≈ 2.03 for {Fe(NO) 2}9), single-crystal X-ray structure (Fe-N(O) and N-O bond distances), and Fe K-edge pre-edge energy (7113.1-7113.3 eV for {Fe(NO) 2}10 vs 7113.4-7113.9 eV for {Fe(NO)2} 9), the 15N NMR spectrum of [Fe(15NO) 2] was also explored to serve as an efficient tool to characterize and discriminate {Fe(NO)2}9 (δ 23.1-76.1 ppm) and {Fe(NO)2}10 (δ -7.8-25.0 ppm) DNICs. To the best of our knowledge, DNIC 5 is the first structurally characterized tetrahedral DNIC formulated as covalent-delocalized [{FeIII(NO-) 2}9-[N(Mes)(TMS)]2-?]. This result may explain why all tetrahedral DNICs containing monodentate-coordinate ligands isolated and characterized nowadays are confined in the {Fe(NO) 2}9 and {Fe(NO)2}10 DNICs in chemistry and biology.

A strategy to improve the performance of cerium(III) photocatalysts

A structural modification strategy to improve the photocatalytic performance of a series of cerium(iii) bis(guanidinate) mono(amide) molecular luminophores was demonstrated. Reducing the steric bulkiness of the amide ligand gave rise to two categories of complexes with distinct photophysical and photochemical properties. A structural parameter, the amide cone angle was applied to differentiate the two categories. Complexes with smaller cone angles ( 173°, category A). And only complexes in the category B could achieve the photocatalytic phenylation of an aryl bromide. These results demonstrated that reducing the steric bulkiness of the amide ligand improved the performance of cerium(iii) bis(guanidinate) mono(amide) photocatalysts in a systematic manner.