58681-16-6

Upstream product

• 2415-79-4 7,7-dibromonorcarane 
• 54043-02-6 ammonium thiophenolate 
• 286-20-4 cyclohexene oxide 
• 3561-67-9 bis(phenylthio)methane 
• 2415-79-4 7,7-dibromonorcarane 
• 108-98-5 thiophenol 

Downstream Products

• 17486-86-1 1,5-diphenylpentan-3-ol 
• 115025-76-8 7-(phenylthio)-7-(trimethylsilyl)bicyclo[4.1.0]heptane 
• 79402-28-1 7-methoxy-7-(phenylthio)bicyclo<4.1.0>heptane 

Relevant academic research and scientific papers

SRN1 Reactions of Halocyclopropanes with Benzenethiolate Ion

Ultraviolet irradiation of gem-dibromocyclopropanes 1 with benzenethiolate ion in liquid ammonia or in Me2SO solutions gave dithioacetals 2 and, in some cases, cyclopropyl phenyl sulfides 3.The reactions did not proceed in the dark and they were inhibited by m-dinitrobenzene, di-tert-butyl nitroxide, and oxygen.The bromocyclopropane 6a underwent a similar, but slower, reaction.Treatment of the bromochlorocyclopropane 7b led to replacement of only the bromine, while the dichlorocyclopropane 9b was inert under the reaction conditions.The results appear consistent with a radical chain mechanism.

Reaction of 7,7-Dibromobicycloheptane and 7-Bromobicycloheptane with Nucleophiles by a Radical Chain Mechanism

7,7-Dibromo- and 7-bromobicycloheptane undergo substitution with certain nucleophiles by a radical chain process.