58687-91-5

Upstream product

• 93-54-9 1-Phenyl-1-propanol 
• 103-65-1 phenylpropane 

Downstream Products

• 102599-43-9 (1-phenyl-propyl)-xanthen-9-yl peroxide 
• 103098-57-3 (+/-)-(1-phenyl-propyl)-trityl peroxide 
• 1565-74-8 (R)-1-phenyl-1-propanol 
• 164200-13-9 (S)-1-phenyl-propyl hydroperoxide 
• 613-87-6 (S)-1-phenyl-1-propanol 
• 190506-77-5 (R)-1-phenyl-propyl hydroperoxide 
• 93-55-0 1-phenyl-propan-1-one 
• 133841-98-2 C₁₅H₂₆O₂Si 

Relevant academic research and scientific papers

AuNP@TiO2 catalyzed peroxidation of Ethyl- and N-Propylbenzene: Exploring the interaction between Radical species and the nanoparticle surface

Ethyl- and n-propylbenzene peroxidation has been studied in the presence of supported gold nanoparticles on TiO2 (AuNP@TiO2). The decomposition products obtained from Fentoninduced cumene hydroperoxide decomposition, as well as the oxidation products of ethyl- and n-propylbenzene, implicate the participation of reactive oxygen species adsorbed on the AuNP surface. This surface intermediate is believed to be a fundamental participant in hydrogen abstraction reactions required to facilitate the formation of the observed carbonyl derived product.

Kinetic resolution of hydroperoxides with enantiopure phosphines: Preparation of enantioenriched tertiary hydroperoxides

An efficient reductive kinetic resolution strategy capable of accessing optically active tertiary hydroperoxides is reported. Readily accessible tertiary hydroperoxides are resolved with commercially available (R)- or (S)-xylyl-PHANEPHOS with selectivity factors as large as 37. The resulting bis(phosphine oxide) can be recycled in high yields. The isolated mono(phosphine oxide) intermediate resolved hydroperoxides with the same selectivity as the parent bisphosphine. Copyright