58692-14-1

Basic information

• Product Name: (1aS,1bR,2aS,6bR)-1a,1b,2a,6b-Tetrahydronaphtho[1,2-b:3,4-b']bisoxirene
• Synonyms: (1aS,1bR,2aS,6bR)-1a,1b,2a,6b-Tetrahydronaphtho[1,2-b:3,4-b']bisoxirene
• CAS NO: 58692-14-1
• Molecular Formula: C₁₀H₈O₂
• Molecular Weight: 160.17
• Mol File: 58692-14-1.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (1aS,1bR,2aS,6bR)-1a,1b,2a,6b-Tetrahydronaphtho[1,2-b:3,4-b']bisoxirene(CAS DataBase Reference)
• NIST Chemistry Reference: (1aS,1bR,2aS,6bR)-1a,1b,2a,6b-Tetrahydronaphtho[1,2-b:3,4-b']bisoxirene(58692-14-1)
• EPA Substance Registry System: (1aS,1bR,2aS,6bR)-1a,1b,2a,6b-Tetrahydronaphtho[1,2-b:3,4-b']bisoxirene(58692-14-1)

Safety Data

• Hazardous Substances Data: 58692-14-1(Hazardous Substances Data)

Upstream product

• 91-20-3 naphthalene 
• 83731-57-1 Trifluoro-acetic acid (1R,2S,3R,4S)-1,4-dibromo-3-(2,2,2-trifluoro-acetoxy)-1,2,3,4-tetrahydro-naphthalen-2-yl ester 
• 83731-56-0 cis-1,2,3,4-Tetrahydro-2,3-bis(trifluoroacetoxy)naphthalin 

Downstream Products

• 3029-30-9 naphthalene-1,4-dicarbonitrile 
• 92-44-4 2,3-naphthalenediol 
• 83731-40-2 Methanesulfonic acid (1S,2R,3S,4R)-3-methanesulfonyloxy-1,4-diphenoxy-1,2,3,4-tetrahydro-naphthalen-2-yl ester 
• 83780-86-3 r,c-1,4-diphenoxy-t,t-2,3-O-isopropylidene-1,2,3,4-tetrahydronaphthalene 
• 83731-38-8 1,4-diphenoxynaphthalene 
• 10075-62-4 1,4-dimethoxynaphthalene 
• 104977-13-1 cis-<1,4-D2>-1,4-Dihydronaphthalin 

Relevant articles and documents

An efficient approach for aromatic epoxidation using hydrogen peroxide and Mn(III) porphyrins

Efficient epoxidation, in very high conversions and selectivities, of aromatic hydrocarbons with hydrogen peroxide, in the presence of Mn III porphyrins [Mn(TDCPP)Cl, Mn(βNO2TDCPP)Cl, Mn(TPFPP)Cl] as catalysts is described; naphthalene and anthracene afford the anti-1,2:3,4-arene dioxides whereas with phenanthrene the 9,10-oxide is obtained.

Hydrogen Transfer Reactions, 9. Synthesis and Analytics of Selectively Deuterated 1,4-Cyclohexadienes and 1,4-Dihydronaphthalenes

Five isotopomers of 1,4-cyclohexadiene (1a - e) and four of 1,4-dihydronaphthalene (2a - d) have been synthesized in an isotopomeric purity sufficient for mechanistic experiments.