58692-14-1Relevant academic research and scientific papers
An efficient approach for aromatic epoxidation using hydrogen peroxide and Mn(III) porphyrins
Rebelo, Susana L. H.,Simoes, Mario M. Q.,Neves, M. Graca P. M. S.,Silva, Artur M. S.,Cavaleiro, Jose A. S.
, p. 608 - 609 (2007/10/03)
Efficient epoxidation, in very high conversions and selectivities, of aromatic hydrocarbons with hydrogen peroxide, in the presence of Mn III porphyrins [Mn(TDCPP)Cl, Mn(βNO2TDCPP)Cl, Mn(TPFPP)Cl] as catalysts is described; naphthalene and anthracene afford the anti-1,2:3,4-arene dioxides whereas with phenanthrene the 9,10-oxide is obtained.
Cobalt(II) porphyrin: A versatile catalyst for the oxidation of organic substrates with dioxygen and 2-methyl propanal
Mandal,Khanna,Iqbal
, p. 3769 - 3772 (2007/10/03)
Cobalt(II)-porphyrin 1 is a versatile catalyst as it promotes the oxidation of wide range of organic substrates at ambient condition by using a combination of molecular oxygen and 2-methyl propanal.
Hydrogen Transfer Reactions, 9. Synthesis and Analytics of Selectively Deuterated 1,4-Cyclohexadienes and 1,4-Dihydronaphthalenes
Brock, Martin,Hintze, Horst,Heesing, Albert
, p. 3718 - 3726 (2007/10/02)
Five isotopomers of 1,4-cyclohexadiene (1a - e) and four of 1,4-dihydronaphthalene (2a - d) have been synthesized in an isotopomeric purity sufficient for mechanistic experiments.
Chemistry of anti- and syn-1,2:3,4-Naphthalene Dioxides and Their Potential Relevance as Metabolic Intermediates
Tsang, Wing-Sum,Griffin, Gary W.,Horning, M. G.,Stillwell, W. G.
, p. 5339 - 5353 (2007/10/02)
The reactivity, site of attack, and stereochemistry of reactions of a variety of nucleophiles with the anti- and syn-1,2:3,4-naphthalene dioxides have been explored.In most cases, substituted tetrahydronaphthalene products arising through attack at the C-1 and C-4 positions in the anti mode were obtained.These isomeric dioxides provide excellent precursors for a number of difficultly accessible 1,4-disubstituted naphthalene derivatives such as 1,4-diphenoxynaphthalene and 1,4-dicyanonaphthalene.Evidence is also presented that anti-naphthalene dioxide constitutes an intermediate metabolite in the rat.
