58751-09-0Relevant academic research and scientific papers
Mechanisms of cage reactions: Kinetics of combination and diffusion after picosecond photolysis of iron(II) porphyrin ligated systems
Traylor, Teddy G.,Magde, Douglas,Luo, Jikun,Walda, Kevin N.,Bandyopadhyay, Debkumar,Wu, Guo-Zhang,Sharma, Vijay S.
, p. 9011 - 9017 (2007/10/02)
The kinetics of transient absorption changes for a number of protoheme-ligand systems after subpicosecond photolysis have been investigated. When the photolyzed ligand is tert-butyl, pentachlorophenyl, pentafluorophenyl, 5α-cholestan-3α-yl, or 5α-cholesta
Synthesis of Pentafluorophenyl Isocyanide and Its Stabilization as a Ligand in Cp*Mn(CO)2(CN-C6F5)
Lentz, Dieter,Graske, Klaus,Preugschat, Dagmar
, p. 1445 - 1448 (2007/10/02)
Pentafluorophenyl isocyanide, C6F5-NC, has been obtained for the first time in analytical pure form by dehydrohalogenation of dibromo-N-(pentafluorophenyl)methanimine, C6F5-N=CBr2, with magnesium in THF.At -30 deg C, C6F5-NC is a crystalline, colourless solid, which readily decomposes on heating to its metaling point of 13 deg C.On reaction with Cp*Mn(CO)2(THF), C6F5-NC can be stabilized by complexation to form Cp*Mn(CO)2(CN-C6F5), the structure of which is elucidated by a crystal structure analsysis.
