58751-79-4

Basic information

• Product Name: N-(Trimethylsiloxy)benzenamine
• Synonyms: N-(Trimethylsiloxy)benzenamine
• CAS NO: 58751-79-4
• Molecular Formula: C₉H₁₅NOSi
• Molecular Weight: 181.31
• Mol File: 58751-79-4.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-(Trimethylsiloxy)benzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(Trimethylsiloxy)benzenamine(58751-79-4)
• EPA Substance Registry System: N-(Trimethylsiloxy)benzenamine(58751-79-4)

Safety Data

• Hazardous Substances Data: 58751-79-4(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 100-65-2 N-Phenylhydroxylamine 

Downstream Products

• 1227476-15-4 Azobenzene 
• 495-48-7 azoxybenzene 

Relevant articles and documents

Asymmetric epoxidation of allylic alcohols catalyzed by vanadium-binaphthylbishydroxamic acid complex

A vanadium-binaphthylbishydroxamic acid (BBHA) complex-catalyzed asymmetric epoxidation of allylic alcohols is described. The optically active binaphthyl-based ligands BBHA 2a and 2b were synthesized from (S)-1,1'-binaphthyl-2,2'dicarboxylic acid and N-substituted-O-trimethylsilyl (TMS)-protected hydroxylamines via a one-pot, three-step procedure. The epoxidations of 2,3,3-trisubstituted allylic alcohols using the vanadium complex of 2a were easily performed in toluene with a TBHP water solution to afford (2R)-epoxy alcohols in good to excellent enantioselectivities.

REACTIONS OF SILYL-SUBSTITUTED CARBANIONS WITH NITRONES

The reaction of carbanions, prepared from 2-(trimethylsilylmethyl)pyridine or N,N-dimethyltrimethylsilylacetamide and lithium diisopropylamide in tetrahydrofuran, with α-aryl-N-phenylnitrones afforded a mixture of corresponding (E)-alkene, azobenzene and azoxybenzene, respectively.On the other hand, the carbanions reacted with cyclic nitrones to give the corresponding aziridine and/or hydroxylamine derivatives as major products.