5877-09-8

Upstream product

• 106-45-6 para-thiocresol 
• 75-56-9 methyloxirane 
• 1200-13-1 1-(p-tolylsulfanyl)propan-2-one 

Downstream Products

• 146300-61-0 (S)-1-(4-methylphenyl)thiopropan-2-ol 
• 404898-26-6 (R)-1-(4-methylphenyl)thiopropan-2-ol 
• 404898-57-3 (R)-1-(4-methylphenyl)thiopropan-2-yl acetate 
• 85870-05-9 1-(4-methylphenylsulfonyl)propan-2-ol 
• 489473-16-7 tert-butyl-dimethyl-(1-methyl-2-p-tolylsulfanyl-ethoxy)-silane 
• 47235-29-0 N-(4-Methyl-phenylmercapto-isopropyl)-N-benzyl-2-chlor-ethylamin 
• 3820-37-9 N-(4-Methyl-phenylmercaptoisopropyl)-N-benzyl-2-hydroxy-aethylamin 
• 5877-17-8 N-(4-Methyl-phenylmercaptoisopropyl)-2-hydroxy-aethylamin 
• 5868-29-1 1-(4-Methyl-phenylmercapto)-2-chlorpropan 

Relevant academic research and scientific papers

Efficient synthesis of-Hydroxy sulfides and-Hydroxy sulfoxides catalyzed by Cu/MgO under solvent-free conditions

Regio-, stereo-, and chemoselective ring opening of epoxides with thiols using Cu/MgO as a heterogeneous catalyst has efficiently been carried out to produce the corresponding β-hydroxy sulfides in excellent yields at room temperature under solvent-free c

LiOH-catalyzed simple ring opening of epoxides under solvent-free conditions

LiOH has been found to be a very simple and selective catalyst for the rapid and mild synthesis of β-hydroxy sulfides and β-hydroxyl nitriles by ring opening of epoxides with aromatic, aliphatic, and heterocyclic thiols and trimethylsilyl cyanide at room temperature under solvent free conditions. All the reactions proceeded satisfactorily in short times and afforded the corresponding products in good to excellent yields with high regioselectivity and chemoselectivity under mild reaction conditions. Copyright Taylor & Francis Group, LLC.

Cyanuric chloride: An efficient catalyst for ring opening of epoxides with thiols under solvent-free conditions

2,4,6-Trichloro-1,3,5-triazine-catalyzed convenient and efficient ring opening of epoxides with thiols under solvent-free conditions is described. Short reaction time, mild reaction conditions, inexpensive and readily available catalyst, and excellent yie

Humicola lanuginosa lipase-catalyzed enantioselective resolution of β-hydroxy sulfides: Versatile synthons for enantiopure β-hydroxy sulfoxides

Humicola lanuginosa lipase-catalyzed acylation of β-hydroxy sulfides provides both the (R)- and (S)-enantiomers in high enantiomeric purity. In two cases the resolved hydroxy sulfides were oxidized to give β-hydroxy sulfoxides in >99% e.e. The effect of substituents on enantioselectivity is discussed.

OXIRANE RING OPENING REACTIONS WITH THIOLS CATALYZED BY LANTHANIDE COMPLEXES

LnCl3 (Ln = Ce,Sm) and Eu(fod)3 act as Lewis-acid catalysts in stereo- and regioselective epoxide ring opening reactions with thiols under mild conditions in CH2Cl2.

Reaction kinetics of β-hydroxyalkyl sulfides with olefin α-oxides

1. The reactions of olefin α-oxides with R β-hydroxyalkyl sulfides are equilibrium reactions. Some of the kinetic parameters of these reactions were determined. 2. An increase in the electron density on the sulfur atom facilitates the progress of the give