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587833-64-5

(1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene)bis(η5-cyclopentadienyl)molybdenum is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 587833-64-5 Structure

  • Basic information

    1. Product Name: (1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene)bis(η5-cyclopentadienyl)molybdenum
    2. Synonyms:
    3. CAS NO:587833-64-5
    4. Molecular Formula:
    5. Molecular Weight: 532.58
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 587833-64-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene)bis(η5-cyclopentadienyl)molybdenum(CAS DataBase Reference)
    10. NIST Chemistry Reference: (1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene)bis(η5-cyclopentadienyl)molybdenum(587833-64-5)
    11. EPA Substance Registry System: (1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene)bis(η5-cyclopentadienyl)molybdenum(587833-64-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 587833-64-5(Hazardous Substances Data)

587833-64-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 587833-64-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 5,8,7,8,3 and 3 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 587833-64:
(8*5)+(7*8)+(6*7)+(5*8)+(4*3)+(3*3)+(2*6)+(1*4)=215
215 % 10 = 5
So 587833-64-5 is a valid CAS Registry Number.

587833-64-5Downstream Products

587833-64-5Relevant articles and documents

Synthesis and crystal structure of N-heterocyclic carbene complexes of bis(η5-cyclopentadienyl)molybdenum

Yamaguchi, Yoshitaka,Oda, Ryoji,Sado, Katsunori,Kobayashi, Kimiko,Minato, Makoto,Ito, Takashi

, p. 991 - 997 (2003)

The one-pot reaction of [Mo(η5-C5H5)2(H)(OTs)] (1) with 1,3-diisopropylimidazolium chloride (IiPr·HCl, 2a) in the presence of two equivalents of KO′Bu in THF gave a bis(η5-cyclopentadienyl)molybdenum derivative bearing the 1,3-diisopropylimidazol-2-ylidene ligand, [Mo(η5-C5H5)2 (IiPr)] (3a). 1,3-Dimethyl- and 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene coordinated molybdenocene complexes (3b, 3c) were prepared in a similar fashion (Method A). The treatment of Mo(η5-C5H5)2(H) Li]4 (6-Mo) with the corresponding imidazolium salt in THF under photo-conditions also gave carbene complexes 3a-3c (Method B). X-ray crystal structure analyses of 3a and 3b revealed that the N-heterocyclic carbene ligand is bonded to a bent molybdenocene skeleton. The Mo-C(carbene) bond distances are 2.219(7) A for 3a and 2.212(6) A for 3b. The five-membered carbene ligand in both complexes is located on the bisecting plane between two cyclopentadienyl rings.

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