58813-48-2

Upstream product

• 97083-12-0 9-phenylethynyl-10-phenylanthracene 
• 100-42-5 styrene 
• 23674-20-6 9-bromo-10-phenylanthracene 
• 121976-02-1 9-phenyl-10-phenylethynyl-9,10-dihydro-anthracene-9,10-diol 

Downstream Products

• 103162-60-3 (1RS,2SR)-1-phenyl-2-(10-phenyl-[9]anthryl)-ethane-1,2-diol 
• 115294-31-0 9-((αRS,βRS)-α,β-dibromo-phenethyl)-10-phenyl-anthracene 
• 103398-51-2 (1RS,2SR)-1,2-diacetoxy-1-phenyl-2-(10-phenyl-[9]anthryl)-ethane 
• 103162-60-3 (1RS,2RS)-1-phenyl-2-(10-phenyl-[9]anthryl)-ethane-1,2-diol 
• 115294-31-0 9-((αRS,βSR)-α,β-dibromo-phenethyl)-10-phenyl-anthracene 

Relevant academic research and scientific papers

Synthesis and characterization of para-pyridine linked NHC palladium complexes and their studies for the Heck-Mizoroki coupling reaction

This paper describes the synthesis of 1-(pyridine-4-ylmethyl) NHC and their Pd(ii) and Ag(i) complexes, which are fully characterized. Interestingly, we have also synthesized a Pd complex 3a-CO3 using a more direct treatment of K2CO3 with PdCl2. 3a-CO 3 represents the first reported solid structure of a Pd η2-carbonato complex stabilized by an NHC framework. 3a-CO 3 can be easily converted to a PdCl2 derivative by treating it with chloroform. We have found these palladium complexes mediate the Heck-Mizoroki coupling with a low catalyst loading. Furthermore, we also expand such catalytic manifold toward constructing fused polyaromatic substrates, a highly useful class of compounds in optoelectronic chemistry.