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589-41-3

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589-41-3 Usage

Chemical Properties

Yellow Oil

Uses

Different sources of media describe the Uses of 589-41-3 differently. You can refer to the following data:
1. Hydroxyurethane is a metabolite of carcinogenic Urethane (U825300).
2. Reactant involved in:Synthesis of molecules used for intermolecular Sharpless aminohydroxylation reactionsIntermolecular ortho-C-H amidation of anilidesCinchona alkaloid-catalyzed asymmetric cycloadditionAllylic arylation
3. Metabolite of carcinogenic Urethane (U825300).

Biochem/physiol Actions

N-Hydroxyurethane causes the chromosomal fragmentation at millimolar concentrations and cell toxicity in cultured normal human leukocytes.

Check Digit Verification of cas no

The CAS Registry Mumber 589-41-3 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,8 and 9 respectively; the second part has 2 digits, 4 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 589-41:
(5*5)+(4*8)+(3*9)+(2*4)+(1*1)=93
93 % 10 = 3
So 589-41-3 is a valid CAS Registry Number.
InChI:InChI=1/C3H7NO3/c1-2-7-3(5)4-6/h6H,2H2,1H3,(H,4,5)

589-41-3 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Aldrich

  • (119474)  N-Hydroxyurethane  

  • 589-41-3

  • 119474-5G

  • 1,533.87CNY

  • Detail
  • Aldrich

  • (119474)  N-Hydroxyurethane  

  • 589-41-3

  • 119474-25G

  • 5,453.37CNY

  • Detail

589-41-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name N-Hydroxyurethane

1.2 Other means of identification

Product number -
Other names ethyl N-hydroxycarbamate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:589-41-3 SDS

589-41-3Relevant articles and documents

An Effective Method for the Synthesis of 1,3-Dihydro-2H-indazoles via N-N Bond Formation

Zhang, Xiaoke,Pan, Yang,Liang, Peng,Ma, Xiaofeng,Jiao, Wei,Shao, Huawu

supporting information, p. 5552 - 5557 (2019/11/22)

The [4+1] cycloaddition reaction of bifunctional amino reagents has been achieved with in situ formed aza-ortho-quinone methides. Specifically, N-(tosyloxy)carbamates were used as an N1 synthon and bifunctional amino reagents for this transformation, which provides a metal-free, catalyst-free, and oxidant-free strategy to form nitrogen-nitrogen bonds. (Figure presented.).

Synthesis of N-Oxyureas by Substitution and Cope-Type Hydroamination Reactions Using O-Isocyanate Precursors

Allen, Meredith A.,Ivanovich, Ryan A.,Polat, Dilan E.,Beauchemin, André M.

supporting information, p. 6574 - 6577 (2017/12/26)

Oxy-carbamate O-isocyanate precursors facilitate access to synthetically valuable N-oxyureas via substitution with amines. This work exploits the reactivity of suitable O-isocyanate precursors, identified by a thorough study highlighting the different reactivity of isocyanate masking groups. This led to bench-stable O-isocyanate precursors, offering improved versatility in the synthesis of N-oxyureas, and demonstrates the controlled reactivity of masked O-isocyanates. Suitable precursors also enabled the first example of Cope-type hydroamination of unsaturated hydroxyureas.

Palladium-Catalyzed Decarboxylative Synthesis of Arylamines

Dai, Qipu,Li, Peihe,Ma, Nuannuan,Hu, Changwen

supporting information, p. 5560 - 5563 (2016/11/17)

A novel approach has been developed for the synthesis of arylamines via the palladium-catalyzed intramolecular decarboxylative coupling (IDC) of aroyloxycarbamates, obtained in situ by reacting aryl carboxylic acids with hydroxycarbamates. The reaction offers facile access to structurally diverse arylamines with the site-specific formation of the C(sp2)-N bond under mild conditions.

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