5895-30-7Relevant academic research and scientific papers
Building blocks for oligomeric siloxanes –selective chlorination of hydrido-siloxanes
Hafner, Thomas,Torvisco, Ana,Uhlig, Frank
, p. 1 - 4 (2018)
A new method was developed to achieve highly selective monochlorination of α,ω-dihydridosiloxanes, ((H)Me2SiO-(SiMe2O)n-SiMe2(H), n = 0–2; (H)R2Si–O-SiR2(H); R = Me, iPr, Ph; 3,5-dihydridooctamethyltetrasiloxane, Me3SiO-(Si(H)MeO)2–SiMe3) with trichloroisocyanuric acid (TCCA). The dependence of the selectivity of the monochlorination on the siloxane chain length is also discussed.
A Convenient Synthesis of α,ω-Difunctionalized Linear Dimethylsiloxanes with Definite Chain Lengths
Yoshino, Koji,Kawamata, Akira,Uchida, Hiroaki,Kabe, Yoshio
, p. 2133 - 2136 (2007/10/02)
α,ω-Difunctionalized linear dimethylsiloxanes with definite chain lengths are conveniently prepared by the inorganic-solid-catalyzed ring cleavage of cyclodimethylsiloxanes with dimethylchlorosilane and water under very mild conditions.
