58954-79-3

Upstream product

• 86728-17-8 methyl 2-phenoxy-2-diethylphosphonoacetate 
• 100-52-7 benzaldehyde 
• 108460-86-2 (Diphenyl-phosphinoyl)-phenoxy-acetic acid methyl ester 
• 2065-23-8 methyl 2-phenoxyacetate 
• 86728-16-7 methyl α-bromo-2-phenoxyacetate 
• 74-88-4 methyl iodide 
• 200404-53-1 [Bis-(2,2,2-trifluoro-ethoxy)-phosphoryl]-phenoxy-acetic acid methyl ester 
• 200404-55-3 [Ethoxy-(2,2,2-trifluoro-ethoxy)-phosphoryl]-phenoxy-acetic acid methyl ester 

Relevant academic research and scientific papers

Stereoselective alkenylation of aldehydes with phosphorus carbanions: Preparation of E- and Z-2-alkoxy- and 2-aryloxy-2-alkenoates

Eighteen phosphorus-based alkenylation reagents 1a-6c were synthesized and condensed with n-butyraldehyde 7a and benzaldehyde 7f. They were condensed with the aldehydes 7b-e,g-n to produce 2-methoxy-2-alkenoates 8a-n and 2-phenoxy-2-alkenoates 9a-n. A dis