59019-10-2Relevant academic research and scientific papers
Synthesis of enaminones containing diverse N,N-disubstitution via simple transamination: a study with sustainable catalyst-free operation
Gao, Yong,Liu, Yunyun,Wei, Li,Wan, Jieping
, p. 5547 - 5555 (2017)
Abstract: A systematic investigation on the synthesis of β-enaminones containing diverse N,N-disubstitution via the transamination of N,N-dimethyl amino functionalized β-enaminones and secondary amines has been conducted by employing biomass available green solvent ethyl lactate as reaction medium. A class of β-enaminones containing different N,N-disubstitutions have been smoothly synthesized under the sustainable conditions without using any catalyst.
Scalable synthesis of enaminones utilizing Gold's reagents
Schuppe, Alexander W.,Cabrera, James M.,McGeoch, Catherine L.B.,Newhouse, Timothy R.
, p. 3643 - 3651 (2017/06/13)
Several Gold's reagents were synthesized from cyanuric chloride and N,N-dialkylformamides. These synthetic equivalents of N,N-dimethylformamide dimethyl acetal were used in an optimized and scalable procedure for the regioselective synthesis of a variety
