5905-01-1Relevant articles and documents
Feasible synthesis of bifurfural from renewable furfural derived 5-bromofurfural for polymerization
Chen, Zhuqi,Lei, Yu,Liao, Yonggui,Yin, Guochuan,Zhu, Jinlian
, (2021)
Deriving versatile monomers from bulky biomass for polymer production can greatly replace fossil resources as the carbon source of chemical industry. The present studies introduce the feasible synthesis of bifurfural, a bifunctionalized bifuran monomer, from the furfural platform. The reaction was carried out through reductive coupling of 5-bromofurfural with CO as the reductant source with commercial Pd/C as the catalyst under gentle conditions, and the catalyst is recyclable and reusable. So prepared bifurfural was preliminarily investigated as a monomer for poly(Schiff base) material synthesis, and it was found that the poly(Schiff base) derived from nonlinear bifurfural monomer polymerizing with linear p-phenylenediamine demonstrated larger surface area than that from petrochemical 4,4′-biphenyldicarboxaldehyde with excellent thermal stability, thus offering a new opportunity in bifurfural based furfural utilization in polymer industry.
Arylation of Aromatic Heterocycles with Arenes and Palladium(II) Acetate
Itahara, Toshio
, p. 5272 - 5275 (2007/10/02)
Treatment of aromatic heterocycles such as furfural, 2-acetylfuran, 2-formylthiophene, 2-acetylthiophene, 1-benzoylpyrrole, 1-(2,6-dichlorobenzoyl)pyrrole, 1-acetylindole, and 1-acetyl-3-methylindole with arenes and palladium(II) acetate gave the corresponding aryl-substituted aromatic heterocycles.