59059-44-8Relevant articles and documents
Radical condensation between benzylic alcohols and acetamides to form 3-arylpropanamides
Azizi, Kobra,Madsen, Robert
, p. 7800 - 7806 (2020/08/14)
A new radical condensation reaction is developed where benzylic alcohols and acetamides are coupled to generate 3-arylpropanamides with water as the only byproduct. The transformation is performed with potassium tert-butoxide as the only additive and gives rise to a variety of 3-arylpropanamides in good yields. The mechanism has been investigated experimentally with labelled substrates, trapping experiments and spectroscopic measurements. The findings indicate a radical pathway where potassium tert-butoxide is believed to serve a dual role as both base and radical initiator. The radical anion of the benzylic alcohol is proposed as the key intermediate, which undergoes coupling with the enolate of the amide to form the new C-C bond. Subsequent elimination to the corresponding cinnamamide and olefin reduction then affords the 3-arylpropanamides.
COMPOUNDS REDUCING MALODOUR PERCEPTION AND THE USE THEREOF
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Page/Page column 55; 56, (2018/09/08)
The present invention relates to new malodour-counteracting agents of formula (I) or stereoisomers thereof, particularly useful in blocking the olfactory perception of androstenone, Formula (I), wherein R1, R2, R3,R4, R5, R6, R7 and X have the same meaning as that defined in the claims. The present invention also relates to consumer products comprising said agents. The present invention also relates to the use of said agents to suppress or attenuate undesirable odour, as well as to methods to suppress or attenuate undesirable odour employing said compounds.
EFFICIENT METHOD FOR THE PREPARATION OF SUBSTITUTED BENZALDEHYDES BY THE OXIDATION OF CYCLOOCTATETRAENE, CYCLOHEPTATRIENE AND THEIR DERIVATIVES BY MOLECULAR OXYGEN IN THE PRESENCE OF PALLADIUM COMPLEXES
Dzhemileva, G. A.,Odinokov, V. N.,Dzhemilev, U. M.
, p. 2165 - 2167 (2007/10/02)
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