5906-74-1Relevant articles and documents
Procedures for the preparation of silanols
Cella, James A.,Carpenter, John C.
, p. 23 - 26 (1994)
Two procedures are described for the preparation of silanols and silanediols from the corresponding chlorosilanes.The first procedure, a two-phase hydrolysis-extraction process, is- particularly convenient and suited to the preparation of a wide range of mono-silanols.Hydrolysis of dichlorosilanes by this procedure gives varied results depending on the structure of the dichlorosilane and specific reaction conditions.The second procedure, a modification of a published procedure, is especially beneficial for the preparation of silanols and silanediols prone to undergo self-condensation. Key words: Silicon; Hydrolysis; Self-condensation; Silanols