59072-88-7

Upstream product

• 60-29-7 diethyl ether 
• 103-72-0 phenyl isothiocyanate 
• 75-03-6 ethyl iodide 
• 636-04-4 N-Phenylbenzothioamide 
• 18263-20-2 thiobenzanilide S-oxide 
• 75-08-1 ethanethiol 

Downstream Products

• 14331-64-7 3,4-diphenyl-1,2,4-triazole 
• 1297270-24-6 3-cyclohexyl-4,5-diphenyl-4H-[1,2,4]triazole 
• 1334385-78-2 3-(1,1-difluoroethyl)-4,5-diphenyl-4H-1,2,4-triazole 
• 1334385-79-3 3,4-diphenyl-5-(trifluoromethyl)-4H-1,2,4-triazole 

Relevant academic research and scientific papers

Organometallic Complex, Light-Emitting Element, Display Device, Electronic Device, and Lighting Device

Provided are organometallic complexes that can exhibit phosphorescence. One of the novel organometallic complexes is represented by General Formula (G1). In General Formula (G1), R1 represents any of an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms which may have a substituent, and an aralkyl group having 7 to 10 carbon atoms which may have a substituent. In addition, R2 represents any of an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms which may have a substituent, and an aryl group having 6 to 12 carbon atoms which may have a substituent. Further, Ar represents an arylene group having 6 to 13 carbon atoms which may have a substituent. Further, M represents a Group 9 element or a Group 10 element.

Organometallic Complex, Light-Emitting Element, Display Device, Electronic Device, and Lighting Device

A novel substance exhibiting phosphorescence is provided. The novel substance is an organometallic complex represented by General Formula (G1). In General Formula (G1), R1 represents a haloalkyl group having 1 to 9 carbon atoms which may have a substituent. In addition, R2 represents any of an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms which may have a substituent, and an aryl group having 6 to 12 carbon atoms which may have a substituent. Further, Ar represents an arylene group having 6 to 13 carbon atoms which may have a substituent. M represents either a Group 9 element or a Group 10 element.

α-Imino sulfenates and α-imino sulfoxides via electrophilic alkylation of amino sulfines (thioamide S-oxides)

Treatment of amino sulfines (thioamide S-oxides) 1 with triethyloxonium tetrafluoroborate, followed by sodium carbonate, leads to α-imino sulfenates 3.Reaction of 3 with primary and secondary amines gives α-imino sulfenamides 5.Treatment of amino sulfines with sodium hydride, followed by an alkyl halide, leads to the formation of α-imino sulfoxides 6, which are extremely sensitive towards hydrolysis.With ketenes, the imines 6 undergo a cycloaddition reaction to give β-lactams 8 in low yield.