59073-20-0Relevant academic research and scientific papers
Generation of Azomethine Ylides via the Desilylation Reaction of Immonium Salts
Padwa, Albert,Haffmanns, Gunter,Tomas, Miguel
, p. 3314 - 3322 (2007/10/02)
Generation of intermediates having azomethine ylide reactivity was achieved by the reaction of several ethanol or thioimidate derivatives with methyl iodide followed by treatment of the resulting imine with (trimethylsilyl)methyl triflate.Desilylation of
CESIUM FLUORIDE INDUCED DESILYLATION REACTION OF IMMONIUM SALTS DERIVED FROM VINYLOGOUS AMIDES
Padwa, Albert,Haffmanns, Gunter,Tomas, Miguel
, p. 4303 - 4306 (2007/10/02)
The cesium fluoride induced desilylation reaction of immonium salts derived from amides, thioamides and vinylogous amides provides access to reactive azomethine ylides in synthetically useful yields.
Alkylation Reactions of Thioamides, VI: Isolation of E- und Z-Thioimidates
Walter, Wolfgang,Ruback, Wulf,Meese, Claus O.
, p. 171 - 182 (2007/10/02)
In a sequence of stereospecific reactions the pure geometric isomers of ortho-substituted methyl thiobenzimidates 3 were prepared from the appropriate thiobenzamides 1.E/Z ratios and barriers to isomerization were determined by means of 1H NMR measurement
