59115-49-0

Basic information

• Product Name: Naphthalene, 2-p-tolyl- (6CI,7CI)
• Synonyms: Naphthalene, 2-p-tolyl- (6CI,7CI);2-(4-Methylphenyl)naphthalene;2-p-Tolylnaphthalene
• CAS NO: 59115-49-0
• Molecular Formula: C₁₇H₁₄
• Molecular Weight: 218.29306
• Mol File: 59115-49-0.mol
• Article Data: 104

Chemical Properties

• Melting Point: 96-97℃
• Appearance: /
• CAS DataBase Reference: Naphthalene, 2-p-tolyl- (6CI,7CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 2-p-tolyl- (6CI,7CI)(59115-49-0)
• EPA Substance Registry System: Naphthalene, 2-p-tolyl- (6CI,7CI)(59115-49-0)

Safety Data

• Hazardous Substances Data: 59115-49-0(Hazardous Substances Data)

Usage

General Description

Naphthalene, 2-p-tolyl- (6CI,7CI) is a chemical compound with the molecular formula C16H12. It is a derivative of naphthalene, which is commonly used in mothballs, pesticides, and various industrial processes. The 2-p-tolyl- substitution indicates the presence of a tolyl group (Tol) at the 2 position of the naphthalene ring. This chemical is primarily used as an intermediate in the synthesis of other organic compounds. It is important to handle and store this chemical with caution, as it can be toxic and harmful if not used properly.

Upstream product

• 54607-04-4 2-(4-methyl-cyclohex-1-enyl)-naphthalene 
• 117271-83-7 2,2,2-triphenyl-1-(2-p-tolyl-1,2-dihydro-[1]naphthyl)-ethanone 
• 59115-35-4 8-methyl-7,8,9,10-tetrahydro-dibenzo[c,h]chromen-6-one 
• 398-49-2 2-trifluoroacetoxynaphthalene 
• 15738-23-5 sodium tetrakis(4-tolyl)borate 
• 66-99-9 β-naphthaldehyde 
• 108-88-3 toluene 
• 624-31-7 4-tolyl iodide 
• 530-93-8 1,2,3,4-tetrahydronaphthalen-2-one 
• 589-92-4 1-methylcyclohexan-4-one 
• 580-13-2 2-bromonaphthalene 
• 5720-05-8 4-methylphenylboronic acid 
• 106-38-7 para-bromotoluene 
• 1503-86-2 2-naphthyl pivalate 

Relevant articles and documents

C(sp2)-C(sp2) cross coupling reaction catalyzed by a water-stable palladium complex supported onto nanomagnetite particles

A water-stable palladium complex supported onto nanomagnetite particles was prepared and characterized. The nanocatalyst showed excellent reusability and activity in aqueous phase processes including the C(sp2)-C(sp2) cross coupling reactions. The advantages of the protocol are its generality, high yields, short reaction time, a cleaner reaction profile, and simplicity.

The Anionic Pathway in the Nickel-Catalysed Cross-Coupling of Aryl Ethers

The Ni-catalysed cross-coupling of aryl ethers is a powerful method to forge new C?C and C?heteroatom bonds. However, the inert C(sp2)?O bond means that a canonical mechanism that relies on the oxidative addition of the aryl ether to a Ni0 centre is thermodynamically and kinetically unfavourable, which suggests that alternative mechanisms may be involved. Here, we provide spectroscopic and structural insights into the anionic pathway, which relies on the formation of electron-rich hetero-bimetallic nickelates by adding organometallic nucleophiles to a Ni0 centre. Assessing the rich co-complexation chemistry between Ni(COD)2 and PhLi has led to the structures and solution-state chemistry of a diverse family of catalytically competent lithium nickelates being unveiled. In addition, we demonstrate dramatic solvent and donor effects, which suggest that the cooperative activation of the aryl ether substrate by Ni0-ate complexes plays a key role in the catalytic cycle.

METHOD FOR SYNTHESIZING BORONATE ESTER COMPOUND, SODIUM SALT OF BORONATE ESTER COMPOUND, AND METHOD FOR SYNTHESIZING THE SAME

An object is to establish a technology with which a boronate ester compound can be easily and efficiently synthesized at a low cost with a small number of steps without the need for a complex chemical method and reagents that need to be carefully handled. A further object is to establish a sodium salt of a boronate ester compound that is a novel compound and a technology for synthesizing the sodium salt of a boronate ester compound. Provided are a sodium salt of a boronate ester compound and a method for synthesizing a boronate ester compound or a sodium salt of a boronate ester compound that includes reacting, in a reaction solvent, an organic chloride with a dispersion product obtained by dispersing sodium in a dispersion solvent to obtain an organic sodium compound, and reacting the obtained organic sodium compound with a borate ester compound to obtain a boronate ester compound or a sodium salt of a boronate ester compound.

METHOD FOR SYNTHESIZING ORGANIC MAGNESIUM COMPOUND, METHOD FOR SYNTHESIZING ORGANIC BORONIC ACID COMPOUND, AND COUPLING METHOD

An object is to establish a technology with which an organic magnesium compound can be easily and efficiently synthesized at a low cost with few steps that do not involve a complex chemical method. A method for synthesizing an organic magnesium compound includes, in a reaction solvent, reacting an organic halide represented by General Formula I (Ra—Xa) with a dispersion product obtained by dispersing sodium in a dispersion solvent to obtain an organic sodium compound represented by General Formula II (Ra—Na), and reacting the obtained organic sodium compound with a magnesium halide represented by General Formula III (Mg—(Xb)2) to obtain an organic magnesium compound represented by General Formula IV (Ra—Mg—Xb).