59115-50-3

Basic information

• Product Name: Naphthalene, 2-methoxy-6-(4-methylphenyl)-
• CAS NO: 59115-50-3
• Molecular Formula: C18H16O
• Molecular Weight: 248.324
• Mol File: 59115-50-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Naphthalene, 2-methoxy-6-(4-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 2-methoxy-6-(4-methylphenyl)-(59115-50-3)
• EPA Substance Registry System: Naphthalene, 2-methoxy-6-(4-methylphenyl)-(59115-50-3)

Safety Data

• Hazardous Substances Data: 59115-50-3(Hazardous Substances Data)

Upstream product

• 106-38-7 para-bromotoluene 
• 177937-97-2 4-methoxy-2-(2-trimethylsilylethynyl)benzaldehyde 
• 67886-70-8 2-cyano-6-methoxynaphthalene 
• 380481-66-3 5,5-dimethyl-2-(4-methylphenyl)-1,3,2-dioxaborinane 
• 5111-65-9 2-Bromo-6-methoxynaphthalene 
• 5720-05-8 4-methylphenylboronic acid 
• 18412-57-2 p-tolyltriethoxysilane 

Relevant articles and documents

Transition-Metal-Free Oxidative Cross-Coupling of Tetraarylborates to Biaryls Using Organic Oxidants

Readily prepared tetraarylborates undergo selective (cross)-coupling through oxidation with Bobbitt's salt to give symmetric and unsymmetric biaryls. The organic oxoammonium salt can be used either as a stoichiometric oxidant or as a catalyst in combination with in situ generated NO2 and molecular oxygen as the terminal oxidant. For selected cases, oxidative coupling is also possible with NO2/O2 without any additional nitroxide-based cocatalyst. Transition-metal-free catalytic oxidative ligand cross-coupling of tetraarylborates is unprecedented and the introduced method provides access to various biaryl and heterobiaryl systems.

Nickel- or Iron-Catalyzed Cross-Coupling of Aryl Carbamates with Arylsilanes

Aryl carbamates were for the first time applied as electrophiles in the cross-coupling with arylsilanes via nickel or iron catalysis to construct valuable biaryl compounds. This new coupling reaction features a good group tolerance and non-sensitivity to steric hindrance on both aryl carbamates and arylsilanes. (Figure presented.).

Carbon - Carbon formation via Ni-catalyzed suzuki - Miyaura coupling through C - CN bond cleavage of aryl nitrile

The Suzuki-Miyaura coupling of aryl nitriles with aryl/alkenyl boronic esters is reported. With this method, the cyano group could be applied as a protecting group of arenes and finally as a leaving group to further construct polyaryl scaffolds.