59117-56-5

Basic information

• Product Name: Benzene, [(1E)-3-(methylthio)-1-propenyl]-
• CAS NO: 59117-56-5
• Molecular Formula: C10H12S
• Molecular Weight: 164.271
• Mol File: 59117-56-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, [(1E)-3-(methylthio)-1-propenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1E)-3-(methylthio)-1-propenyl]-(59117-56-5)
• EPA Substance Registry System: Benzene, [(1E)-3-(methylthio)-1-propenyl]-(59117-56-5)

Safety Data

• Hazardous Substances Data: 59117-56-5(Hazardous Substances Data)

Upstream product

• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 5188-07-8 sodium thiomethoxide 
• 56504-14-4 S-methyl S-<1-(1-phenylprop-2-enyl)> dithiocarbonate 
• 56504-08-6 O-cinnamyl S-methyl dithiocarbonate 
• 4392-24-9 Cinnamyl bromide 

Downstream Products

• 16215-16-0 (E)-(3-(methylsulfonyl)prop-1-en-1-yl)benzene 
• 10477-16-4 1-Chlor-1--2-phenyl-buta-1,3-dien 

Relevant articles and documents

Molecular orbital studies on pericyclic reactions of cinnamyl xanthates in β-cyclodextrin cavities

The solid β-cyclodextrin (β-CyD) complex of O-cinnamyl S-methyl dithiocarbonates (xanthate, 1a), upon heating at 45°C, underwent asymmetric [3,3]-sigmatropic rearrangement to give the optically S-(1-phenylallyl) S-methyl dithiocarbonate (2a) with 60% ee.

Catalytic behavior of phenols in pyrolytic conversion of allylic dithiolcarbonates to allylic sulfides

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Homogenous Catalysis. Production of Allyl Alkyl Sulphides by Palladium Mediated Allylation

The use of O-allyl S-alkyl dithiocarbonate substrates in palladium mediated catalytic allylation gives carbonyl sulphide and allyl alkyl sulphides with net retention of configuration and their use obviates the problems associated with sulphur nucleophiles in catalytic allylation.