Molecular orbital studies on pericyclic reactions of cinnamyl xanthates in β-cyclodextrin cavities

DOI: 10.1248/cpb.48.1652

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1652 - 1659 (2000)

Update date:2022-08-11

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Authors:

Eto Eto

Kubota Kubota

Nakagawa

Yoshitake

Harano Harano

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Article abstract of DOI:10.1248/cpb.48.1652

The solid β-cyclodextrin (β-CyD) complex of O-cinnamyl S-methyl dithiocarbonates (xanthate, 1a), upon heating at 45°C, underwent asymmetric [3,3]-sigmatropic rearrangement to give the optically S-(1-phenylallyl) S-methyl dithiocarbonate (2a) with 60% ee.

Full text of DOI:10.1248/cpb.48.1652

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