Molecular orbital studies on pericyclic reactions of cinnamyl xanthates in β-cyclodextrin cavities

DOI: 10.1248/cpb.48.1652

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1652 - 1659 (2000)

Update date:2022-08-11

Topics:

Authors:

Eto Eto

Kubota Kubota

Nakagawa

Yoshitake

Harano Harano

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.48.1652

The solid β-cyclodextrin (β-CyD) complex of O-cinnamyl S-methyl dithiocarbonates (xanthate, 1a), upon heating at 45°C, underwent asymmetric [3,3]-sigmatropic rearrangement to give the optically S-(1-phenylallyl) S-methyl dithiocarbonate (2a) with 60% ee.

Full text of DOI:10.1248/cpb.48.1652

NII-Electronic Library Service

Products guided by the article

Product name:Benzene, [(1E)-3-(methylthio)-1-propenyl]-

Cas No:59117-56-5

R&D Labs maybe for 59117-56-5

LINYI FUDE FINE CHEMICAL CO.,LTD

Contact:86-539-2361184

Address:YISHUI, LINYI,SAHNDONG,CHINA
Tianjin Ji Ping Jia Chemical Co., Ltd.

Contact:18622448868

Address:tianjin
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)

Contact:+86-571-56880228

Address:15F Guodu development Building, NO.182 Zhaohui Road
Hunan Haili Chemical Industry Co.,Ltd.

Contact:+86-731-85521860

Address:No.251, 2nd Section, Furong Road, Changsha,Hunan,China
WUXI HONOR SHINE CHEMICAL CO.,LTD

Contact:+86-510-83593312

Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )

Relevant to this article

Experimental study of hydrogen bonding potentially stabilizing the 5'-deoxyadenosyl radical from coenzyme B₁₂

Doi:10.1002/chem.201201840
(2012)
Structural and Mechanistic Insights into s-Block Bimetallic Catalysis: Sodium Magnesiate-Catalyzed Guanylation of Amines

Doi:10.1002/chem.201602906
(2016)
Doi:10.1016/S0020-1693(00)81615-1
(1985)
Multifunctional polymer nanoparticles: Ultra bright near-infrared fluorescence and strong magnetization and their biological applications

Doi:10.1039/c6ra07520g
(2016)
CATALYTIC CARBONYLATION OF NITRO COMPOUNDS IN THE PRESENCE OF CARBONYL IONIC COMPLEXES OF Rh(I), Ir(I), Pd(I), AND Pd(II)

Doi:10.1007/BF00948996
(1984)
PURIFICATION AND CHARACTEIZATION OF (S)-TETRAHYDROBERBERINE OXIDASE FROM CULTURED COPTIS JAPONICA CELLS

Doi:10.1016/0031-9422(88)80255-3
(1988)

Article Doi