591250-18-9

Upstream product

• 75-36-5 acetyl chloride 
• 528861-97-4 methyl 3-(5-chloro-2-nitrophenyl)-3-hydroxy-2-methylenepropanoate 
• 6628-86-0 5-chloro-2-nitrobenzaldehyde 

Downstream Products

• 910456-68-7 4-benzoyl-3-(5-chloro-2-nitro-phenyl)-2-methylene-5-oxo-hexanoic acid methyl ester 
• 910456-78-9 2-acetyl-3-(5-chloro-2-nitro-phenyl)-4-methylene-pentanedioic acid 1-ethyl ester 5-methyl ester 

Relevant academic research and scientific papers

Synthesis of 3-substituted quinolines via transition-metal-catalyzed reductive cyclization of o-nitro baylis-hillman acetates

Reductive cyclization of o-nitro-substituted Baylis-Hillman acetates by carbon monoxide, catalyzed by [Cp*Fe(CO)2]2, gives moderate to good yields of 3-substituted quinolines.

Synthesis of substituted 1H- and 3H-1-benzazepines and rearrangement of alkyl 1H-1-benzazepine-2-carboxylates into isoquinolines

The SnCl2-mediated reduction of nitro groups in 2-nitro-4-(2-nitrobenzylidene)alkanoates and 4-nitro-2-(2-nitroalkylidene) alkanoates allows the facile synthesis of substituted 1H-1-benzazepines and 3H-1-benzazepines. This reaction proceeds via

An alternate approach to quinoline architecture via Baylis-Hillman chemistry: SnCl2-mediated tandem reaction toward synthesis of 4-(substituted vinyl)-quinolines

An alternate approach to densely substituted quinolines from the products of SN2 nucleophilic substitution reaction between the acetyl derivatives of the Baylis-Hillman adducts obtained from 2-nitrobenzaldehydes and the carbonyl group containin