591732-85-3Relevant academic research and scientific papers
Anion Binding in Water Drives Structural Adaptation in an Azaphosphatrane-Functionalized FeII4L4 Tetrahedron
Zhang, Dawei,Ronson, Tanya K.,Mosquera, Jesús,Martinez, Alexandre,Guy, Laure,Nitschke, Jonathan R.
, p. 6574 - 6577 (2017)
Anion-templated aqueous self-assembly resulted in the formation of an endohedrally functionalized FeII4L4 tetrahedron from azaphosphatrane-based subcomponents. This new water-soluble cage is flexible and able to encapsulate anions with volumes ranging from 35 to 219 ?3 via hydrogen bonding and electrostatic interactions. It structurally adapts in response to the size and shape of the template anions, dynamically adopting a conformation either where all four azaphosphatrane +P-H vectors point inward, or else where one points outward and the other three inward. The two cage isomers can coexist in solution and interconvert. A shape memory phenomenon was observed during guest displacement because guest exchange occurs more rapidly than structural reconfiguration.
Influence of the cavity dimension on encapsulation of halides within the capsular assembly and side-cleft recognition of a sulfate-water cluster assisted by polyammonium tripodal receptors
Manna, Utsab,Nayak, Biswajit,Hoque, Md. Najbul,Das, Gopal
, p. 5036 - 5044 (2016/07/07)
The p-nitrophenyl and p-bromophenyl functionalized tris-polyamine receptors, L1 and L2, have formed capsular assembly with halide ions in an encapsulated fashion through efficient hydrogen-bonding. On the other hand, the positional isomer of L1, the m-nitrophenyl functionalized tripodal amine receptor L3, displays a rather flat-open conformation and is unable to bind halide anions in an encapsulated form. The presence of a smaller cavity in these receptors hinders the binding of larger oxyanions like sulfate. As a result, the protonated tripodal scaffold encapsulates small solvent molecules and helps in side-cleft binding of the larger sulfate anion. Herein, we report the design, synthesis and characterization of tren-based polyammonium receptors L1, L2 and L3 and their complexation as well as binding discrepancy with several anions in the presence of acid. The solid state crystal structure of the anion complexes with L1, L2 and L3 reveal that the anions are recognized via stable N-H?A, C-H?A, anion-π interactions with the protonated receptor molecule in a unimolecular fashion either inside or outside the cavity. The sulfate-water complexes of receptors L1, L2 and L3 are stabilized by (NH)+?O type H-bonding and electrostatic interactions among sulfate, water and ammonium groups. The polyammonium based tripodal scaffold with positional variation of the functional group shows significant difference in anion binding fashion through either capsular or non-capsular complex formation.
