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η6-[(4-chlorophenyl)benzene]tricarbonylchromium(0) is an organometallic compound consisting of a chromium atom bonded to a benzene ring with a 4-chlorophenyl substituent, and three carbonyl ligands. This complex is characterized by its unique electronic structure and stability, which arises from the η6 coordination mode of the benzene ring to the chromium center. The presence of the 4-chlorophenyl group introduces a halogenated aromatic system, which can influence the compound's reactivity and electronic properties. The tricarbonylchromium(0) moiety is a common structural motif in organometallic chemistry, often associated with catalytic activity and electronic effects. η6-[(4-chlorophenyl)benzene]tricarbonylchromium(0) is of interest in the field of organometallic chemistry, potentially for its applications in catalysis or as a precursor in the synthesis of more complex organometallic systems.

59183-97-0

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59183-97-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 59183-97-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,9,1,8 and 3 respectively; the second part has 2 digits, 9 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 59183-97:
(7*5)+(6*9)+(5*1)+(4*8)+(3*3)+(2*9)+(1*7)=160
160 % 10 = 0
So 59183-97-0 is a valid CAS Registry Number.

59183-97-0Downstream Products

59183-97-0Relevant academic research and scientific papers

Palladium catalysed cross-coupling of (fluoroarene)tricarbonyl-chromium(o) complexes

Wilhelm, Rene,Widdowson, David A.

, p. 3808 - 3813 (2007/10/03)

(Fluoroarene)tricarbonylchromium(o) complexes were found to undergo Suzuki and Stille cross-coupling reactions to form functionalised biaryl and styrene complexes in up to 87 and 52% yields, respectively. The Suzuki reactions were optimal with dipalladium tris(dibenzylideneacetone)-trimethylphosphine-caesium carbonate in DME at reflux. The Stille reactions were optimal with dipalladium tris(dibenzylideneacetone)-trimethylphosphine-caesium fluoride in DME at reflux and neither was adversely affected by a methoxy group on the complexed ring. The Suzuki reaction tolerated a chloro group on the arylboronic acid ring but not a bromo group. The Royal Society of Chemistry 2000.

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