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59229-75-3

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59229-75-3 Usage

Definition

ChEBI: A member of the class of amino-nitrotoluenes that is 2,6-diaminotoluene bearing a nitro substituent at position 4.

Check Digit Verification of cas no

The CAS Registry Mumber 59229-75-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,9,2,2 and 9 respectively; the second part has 2 digits, 7 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 59229-75:
(7*5)+(6*9)+(5*2)+(4*2)+(3*9)+(2*7)+(1*5)=153
153 % 10 = 3
So 59229-75-3 is a valid CAS Registry Number.
InChI:InChI=1/C7H9N3O2/c1-4-6(8)2-5(10(11)12)3-7(4)9/h2-3H,8-9H2,1H3

59229-75-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,6-diamino-4-nitrotoluene

1.2 Other means of identification

Product number -
Other names 1,3-Benzenediamine, 2-methyl-5-nitro-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:59229-75-3 SDS

59229-75-3Downstream Products

59229-75-3Relevant articles and documents

A simple synthesis of 2,6-diamino-4-nitrotoluene

Eturi, Sreenivasa R.,Iyer, Sury

, p. 2431 - 2434 (1999)

A two-step facile synthesis of 2,6-diamino-4-nitrotoluene (1) is described via a sequential selective reduction of nitro groups from trinitrotoluene (TNT).

Effect of adsorption to elemental iron on the transformation of 2,4,6-trinitrotoluene and hexahydro-1,3,5-trinitro-1,3,5-triazine in solution

Oh, Seok-Young,Cha, Daniel K.,Kim, Byung J.,Chiu, Pei C.

, p. 1384 - 1389 (2007/10/03)

The effect of adsorption to elemental iron on the reductive transformation of 2,4,6-trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazine (royal demolition explosive [RDX]) in aqueous solution was studied with scrap iron and high-purity iron. In batch experiments with the same total iron surface area and a mixing rate of 100 rpm, TNT and RDX were removed from the solution within 30 min. With high-purity iron, adsorbed TNT was reduced to 2,4,6-triaminotoluene (TAT) rapidly, with little accumulation of intermediates at the surface. With scrap iron, the extent of adsorption of TNT and its daughter products was more significant and reduction of these adsorbed molecules to TAT was slower. Distribution of the intermediates indicated that the reaction with scrap iron occurred primarily through reduction of the ortho nitro group. Kinetic analysis suggests that mass transfer or adsorption of TNT controlled the overall rate of TNT reduction to TAT with pure iron, whereas with scrap iron, the rate of TAT formation was probably limited by other processes. Compared to TNT, transformation of adsorbed RDX was more rapid and less affected by iron type. The RDX was reduced to an unidentified, water-soluble intermediate and NH4+, which accounted for approximately 50% of the RDX nitrogen. No total organic carbon reduction was observed before and after RDX transformation with scrap iron.

Highly selective one-step synthesis of 2-amino-4,6-dinitrotoluene and 2,6-diamino-4-nitrotoluene from 2,4,6-trinitrotoluene

Shevelev,Shakhnes,Ugrak,Vorob'ev

, p. 2557 - 2561 (2007/10/03)

Selective method of reduction of the ortho-nitro groups in 2,4,6-trinitrotoluene by hydrazine hydrate in the presence of FeCl3 and charcoal has been elaborated. This method allows obtaining either 2-amino-4,6-dinitrotoluene or 2,6-diamino-4-nit

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