5925-75-7Relevant articles and documents
Processes for preparing carbapenem derivatives
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, (2008/06/13)
The invention relates to carbapenem derivatives useful as antimicrobial agents, more particularly to intermediate compounds for the preparations thereof of the formula STR1
Acid-Catalyzed Hydrolysis of Ketene Dithioacetals and Trithioorthocarboxylates. Effect of β-Methyl Substitution
Okuyama, Tadashi,Kawao, Shoji,Fueno, Takayuki
, p. 85 - 88 (2007/10/02)
Hydrolysis rates of β-methyl-substituted ketene dithioacetals were measured. β-Monomethyl and β,β-dimethyl substitutions reduced the reactivity of the parent acetal by factors of 26 and 6.7 x 105, respectively.Similar methyl substitutions of trithioorthoacetate, however, enhanced the hydrolysis reactivity by 3 and 23 times.The reversibility of protonation of ketene dithioacetal during hydrolysis was slightly increased by a β-methyl group, but dimethyl substitution seemed to inhibit reversibility by raising the potential barrier to protonation.
ACTION DE L'OZONE SUR DES DERIVES VINYLIQUES; REACTIONS CONSERVANT L'ENCHAINEMENT CARBONE.
Strobel, Marie-Paule,Morin, Luc,Paquer, Daniel
, p. 523 - 524 (2007/10/02)
Ozone reacts with vinyl derivatives (sulphides, enamines, ethers) and gives abnormal reactions or/and double bond cleavages.