592532-93-9

Upstream product

• 76-83-5 trityl chloride 
• 592532-92-8 1-(2,3-di-O-benzyl-L-arabinofuranosyl)-2-propanol 

Downstream Products

• 592532-96-2 Thioacetic acid S-[(2R,3R,4S)-3,4-bis-benzyloxy-5-(2-oxo-propyl)-tetrahydro-furan-2-ylmethyl] ester 
• 592532-95-1 1-(2,3-di-O-benzyl-L-arabinofuranosyl)-acetone 
• 592532-94-0 1-(2,3-di-O-benzyl-5-O-trityl-L-arabinofuranosyl)-acetone 

Relevant academic research and scientific papers

Synthesis of thio-C-glycosides from 2′-carbonylalkyl C-glycosides by a tandem β-elimination and intramolecular hetero-Michael addition

2′-Carbonyl 5-S-acetyl-C-glycofuranosides and 2′-carbonyl 4-S-acetyl-C-glycopyranosides were converted in good yields to respective 5-thio-C-glycopyranosides and 4-thio-C-glycofuranosides under base treatment. The transformation was resulted from β-elimin

Epimerization of 2'-carbonylalkyl-C-glycosides via enolation, beta-elimination and intramolecular cycloaddition.

Treatment of 2'-carbonyl-alpha-C-glycopyranosides of gluco, galacto, manno, 2-deoxy, and 2-azido sugars with 4% NaOMe resulted in anomeric epimerization to give their respective beta-anomers in good to excellent yields. The epimerization of the 2'-aldehyd