593-39-5Relevant articles and documents
Bioactive tigliane diterpenoids from the latex of Euphorbia fischeriana
Deng, Yan-Yan,Qu, Bo,Zhan, Zhong-Lang,Wang, An-Qi,Zhou, Wei,Jia, Ming-Yue,Hua, Juan,Luo, Shi-Hong
supporting information, p. 179 - 187 (2021/01/12)
Latex is a type of sticky endogenous fluids derived from diverse plants including Euphorbia fischeriana, and is of great scientific and commercial values. In the current study, it was demonstrated that the latex extracted from E. fischeriana strongly respelled the growth of cotton bollworm, Helicoverpa armigera. Using spectroscopic methods, HPLC, and GC-MS analyses, six aliphatic tigliane diterpenoids were isolated from the latex of E. fischeriana, among which three compounds (2, 3, and 5) were new. Two major compounds (1 and 4) exhibited remarkable antifeedant activity against H. armigera, with EC50 values at 2.59 and 15.32 μg/cm2, respectively. In addition, the quantification analysis of diterpenoids in different organs indicated that 4 was the most abundant constituent and was highly accumulated in the latex. Collectively, the current study highlighted that the diterpenoids in latex of E. fischeriana had a considerable antifeedant function against H. armigera, which might be employed for the future development of natural insecticides for organic farming.
Phosphonium Iodide in Organic Synthesis
Chatterjea, J. N.,Majee, R. N.,Mukherjee, S. N.
, p. 733 - 735 (2007/10/02)
Phosphonium iodide is found useful in the stereospecific conversion of some vicinal diols to olefins.Synthesis of cis-hexadec-9-enolide has been achieved.
