59305-32-7

Usage

InChI:InChI=1/C18H36Si3/c1-19(2,3)13-16-10-17(14-20(4,5)6)12-18(11-16)15-21(7,8)9/h10-12H,13-15H2,1-9H3

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 17299-97-7 α,α',α''-trichloromesitylene 
• 85014-36-4 1,3-dimethyl-5-methylenecyclohexane 
• 108-67-8 1,3,5-trimethyl-benzene 
• 13361-64-3 trimethyl(propargyl)silane 
• 1822-00-0 trimethylsilylmethyllithium 
• 151600-02-1 6-bromo-2-naphthalenyl trifluoromethanesulfonate 

Relevant academic research and scientific papers

Synthesis, crystal structures, and redox behavior of some pentamethylcyclopentadienyl arene ruthenium salts

Hexafluorophosphates of (η5-pentamethylcyclopentadienyl)(h6- arene)ruthenium cations (arene = 1,3,5-triethylbenzene, 1,3,5- tris(trimethylsilylmethyl)benzene, and pentamethylbenzene) have been obtained from the reaction of [Ru(η5-Cs

Palladium-catalyzed C(sp 3)-C(sp 2) cross-coupling of (trimethylsilyl)methyllithium with (hetero)aryl halides

The palladium-catalyzed direct cross-coupling of a range of organic chlorides and bromides with the bifunctional C(sp3)-(trimethylsilyl)methyllithium reagent is reported. The use of Pd-PEPPSI-IPent as the catalyst allows for the preparation of structurally diverse and synthetically versatile benzyl- and allylsilanes in high yields under mild conditions (room temperature) with short reaction times.

Cyclotrimerization of Alkynes using as Activated Zirconium-Titanium Catalyst Prepared by the Reduction of Zirconium Tetrachloride and Titanium Trichloride with Lithium Powder

Activated zirconium-titanium prepared by the reduction of zirconium tetrachloride and titanium trichloride with lithium efficiently catalyses the cyclotrimerization of alkynes.

Main Group Conjugated Organic Anion Chemistry. 3. Application of Magnesium-Anthracene Compounds in the Synthesis of Grignard Reagents

Reaction of magnesium-arene compounds, , 1, and some silylanthracene, and/or tertiary amine analogues, with benzylic and allylic chlorides or bromides, and (Me3Si)3CCl, afford Grignard reagents, RMgX, in modest to high yield for chlorides and negligible to high yield for the bromides, in THF, toluene, and hexane at -10 to 20 deg C.Novel benzylic-type Grignard reagents prepared in high yield include those of 9-(chloromethyl)anthracene, 2-(chloromethyl)pyridine and 8-(chloro(or bromo)methyl)quinoline, and poly-Grignard reagents derived from 1,8-bis(chloromethyl)naphthalene, 2,2'-bis(chloromethyl)-1,1'-binaphthyl, and 1,3,5,-tris(chloro(or bromo)methyl)benzene.Grignard reagent formation occurs via electron-transfer reactions.Aryl and alkyl halides yield mainly products derived from addition of the halide across the 9,10-positions of the anthracenes, via nucleophilic substitution or collapse of a diradical cage 2+, (anthracene)-anion radical, RX-anion radical.>

The Metallation-Elimination Reaction, II. Monocyclic Anions and Polyanions

Equimolar mixtures of n-butyllithium and potassium tert-amyloxide effect metallation and metal hydride elimination of cyclic olefins directly to give conjugated anions and polyanions in a single operation. 1-Methyl-1-cycloalkenes or methylenecycloalkanes are particularly well suited and give highly unsaturated products.Odd-membered rings eliminate better than their even-membered counterparts, and eight-membered rings eliminate particularly slowly.Reactions with methyl iodide and trimethylsilyl chloride proceed smoothly in high yield.