59311-27-2Relevant articles and documents
Model compounds based on poly(p-phenylenevinyleneborane) and terthiophene: Investigating the p-n junction in diblock copolymers
Hinkens, Diane M.,Chen, Qiliang,Siddiki, Mahbube Khoda,Gosztola, David,Tapsak, Mark A.,Qiao, Qiquan,Jeffries-El, Malika,Darling, Seth B.
, p. 3510 - 3520 (2013)
Conjugated block copolymers represent a class of materials with potential applications in electronics and optoelectronics. Three block copolymer model compounds were made by first synthesizing 5-ethynyl-2,2′:5′, 2″-terthiophene, 5-(2-propynyl)-2,2′:5′,2″-terthiophene and 5-(3-butynyl)-2,2′:5′,2″-terthiophene and then performing hydroboration polymerization from the alkyne of the terthiophene. The impact of the connectivity between the polymer blocks of these compounds was investigated. Theoretical and experimental studies indicated that charge transfer was occurring within the all-conjugated copolymer model compound, and that electronic coupling decreased with increasing length of the linking bridge between the n-type and p-type materials. Preliminary efforts to synthesize the related regioregular poly(3-hexylthiophene) all-conjugated diblock copolymer and use this material as the active layer in photovoltaic cells are discussed.
Preparation method of 2-(4-fluorophenyl)-5-[(5-bromo-2-methylphenyl)methyl]thiophene
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Paragraph 0037-0039; 0049-0051; 0059-0061, (2020/04/17)
The invention belongs to the field of chemistry, and particularly relates to a novel synthesis method of a key intermediate 2-(4-fluorophenyl)-5-[(5-bromo-2-methylphenyl)methyl]thiophene for preparinga medicine canagliflozin for treating type 2 diabetes mellitus. Cheap and easily available 2-methylthiophene used as an initial raw material undergoes five steps of halogenation, p-nitrotoluene alkylation, coupling, nitro reduction and a Sandmeyer reaction to prepare the product. The method has the characteristics of simplicity in operation, high reaction selectivity, few byproducts and high product quality.
Vinyl-triarylated amine conjugated charge transportation material and preparation method thereof
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Paragraph 0098, (2017/07/21)
The invention discloses a vinyl-triarylated amine conjugated charge transportation material and a preparation method thereof. The chemical structural formula of the vinyl-triarylated amine conjugated charge transportation material is shown in the formula