593286-38-5

Upstream product

• 2468-55-5 5-iodopent-1-yne 
• 10424-93-8 N'-cyclohexylidene-N,N-dimethyl-hydrazine 
• 541-41-3 chloroformic acid ethyl ester 
• 855300-62-8 6-pent-4-ynyl-1,4-dioxa-spiro[4.5]decane 
• 108-94-1 cyclohexanone 
• 42797-81-9 2-(pent-4-ynyl)cyclohexanone 

Relevant academic research and scientific papers

New cascade reactions starting from acetylenic ω-ketoesters: An easy access to electrophilic allenes and to 1,3-bridgehead ketones

Acetylenic ω-ketoesters bearing a three carbon-carbon bond spacer reacted smoothly with tetra-n-butylammonium fluoride and with potassium tert-butoxide to afford either electrophilic allenes or 1,3-bridgehead ketones, the latter being potentially useful m

Intramolecular reductive ketone-alkynoate coupling reaction promoted by (η2-propene)titanium

Intramolecular reductive coupling of cycloalkanones tethered to alkynoates in the presence of (η2-propene)titanium was successfully performed to provide hydroxy-esters in a diastereoselective manner. Subsequent lactonization afforded angularly

Controlled synthesis of α-allenic ester and spiro ketone derivatives from tailored α-substituted cycloalkanones through cascade reactions: Exploring the possible reaction pathways by means of semiempirical MO calculations

Functionalized bicyclic electrophilic allenes and (or) spiro ketones have been obtained through a cascade reaction when acetylenic ω-keto esters were treated with tetra-n-butylammonium fluoride (TBAF). The isolated products can be modulated by using diffe