59363-22-3

Upstream product

• 56438-59-6 2-[2-(4-methoxyphenyl)-ethyl]oxirane 
• 67-64-1 acetone 
• 20574-98-5 4-(p-methoxyphenyl)but-1-ene 

Downstream Products

• 59364-86-2 1-[2-(2,4-dichloro-phenyl)-4-(4-methoxy-phenethyl)-[1,3]dioxolan-2-ylmethyl]-1H-imidazole 
• 59365-71-8 2-Bromomethyl-2-(2,4-dichloro-phenyl)-4-[2-(4-methoxy-phenyl)-ethyl]-[1,3]dioxolane 
• 1929-29-9 3-(4-methoxyphenyl)propanoic acid 

Relevant academic research and scientific papers

Silver(I)-Catalyzed Widely Applicable Aerobic 1,2-Diol Oxidative Cleavage

The oxidative cleavage of 1,2-diols is a fundamental organic transformation. The stoichiometric oxidants that are still predominantly used for such oxidative cleavage, such as H5IO6, Pb(OAc)4, and KMnO4, generate stoichiometric hazardous waste. Herein, we describe a widely applicable and highly selective silver(I)-catalyzed oxidative cleavage of 1,2-diols that consumes atmospheric oxygen as the sole oxidant, thus serving as a potentially greener alternative to the classical transformations.

2-Aryl-2-halomethyl-4-alkenyl-1,3-dioxolanes

Novel compounds denoted as 2-aryl-2-halomethyl-4-alkenyl-1,3-dioxolanes used as intermediates in making 1-(2-Ar-4-R-1,3-dioxolan-2-ylmethyl)imidazoles, useful as antifungal and antibacterial agents.

1,3-Dioxolan-2-ylmethylimidazoles

Novel 1-(2-Ar1 -4-Ar2 -1,3-dioxolan-2-ylmethyl)imidazoles, 1-[2-Ar1 -4-(Ar2 -oxymethyl)-1,3-dioxolan-2-ylmethyl]imidazoles, 1-[2-Ar1 -4-(Ar2 -thiomethyl)-1,3-dioxolan-2-ylmethyl]imidazoles,